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作者:

Liang, Yixuan (Liang, Yixuan.) | Zhang, Qiyu (Zhang, Qiyu.) | Li, Sumei (Li, Sumei.) | Fei, Jiaying (Fei, Jiaying.) | Zhou, Jian (Zhou, Jian.) (学者:周剑) | Shan, Saisai (Shan, Saisai.) | Li, Ziyi (Li, Ziyi.) | Li, Hanbing (Li, Hanbing.) | Chen, Sha (Chen, Sha.) (学者:陈莎)

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EI Scopus SCIE

摘要:

As anthropogenic antibiotics, quinolones, e.g., ofloxacin have adverse impacts on ecological systems and human heaths. The removal of quinolones is of great importance, and adsorption techniques have been widely used to remove this hazardous contaminant. However, a robust and easy-operating adsorbent is still emergently required due to the complex chemical structure of quinolones. In this study, we successfully synthesized the promising metallic carbons (MCs) containing carbon nanotubes and cobalt nanoparticles by carbonizing Zn/Co-ZIF at 900 degrees C. Three different molar ratios of Co and Zn were applied to optimize the adsorption capacity on ofloxacin (OFL). Results showed MC with molar ratio of Co and Zn at 3:1 (Co-CNT/NPC3/1) achieved the maximal adsorption capacity to 118.3 mg g-1. Its adsorption performance was satisfied in the pH range from 5 to 9 and ionic strengths at 0.01 M. The main mechanisms for these adsorptions were identified as electrostatic attraction, metal coordination and pi-pi EDA. Removal efficiencies of quinolones higher than 68 mg g-1 indicated the strong feasibility of this adsorbent for wastewater treatments. The regeneration of Co-CNT/NPC3/1 at 600 degrees C allowed its at least 4-time reusability and its magnetic property enabled external magnets to recycle it from real environments.

关键词:

Magnetic separation Adsorption Zn Co zeolitic imidazolate frameworks Metallic carbides

作者机构:

  • [ 1 ] [Liang, Yixuan]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Qiyu]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Sumei]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Fei, Jiaying]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Shan, Saisai]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Ziyi]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Li, Hanbing]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 8 ] [Chen, Sha]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 9 ] [Zhou, Jian]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 陈莎

    [Chen, Sha]Beijing Univ Technol, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF HAZARDOUS MATERIALS

ISSN: 0304-3894

年份: 2022

卷: 423

1 3 . 6

JCR@2022

1 3 . 6 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:49

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 38

SCOPUS被引频次: 40

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 3

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