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摘要:
Taking the advantage of the low transition barrier between P4bm and P4mm distortions, tetragonal structured 0.875Bi(0.5)Na(0.5)TiO(3)-0.125BaTiO(3) was designed to construct an electrocaloric ceramics with large electrocaloric strength by adding the third compound Bi(Mg0.5Ti0.5)O-3 (BMT). The experiments show that, through adding 2.5 mol.% BMT, a large Delta T of 0.80 K was directly observed under 4 kV/mm; especially, a high Delta T/Delta E of 0.020-0.023 K cm/kV was achieved, approximate to BaTiO3-based and some lead-based relaxors. The high electrocaloric effect is attributed to that the 2.5 mol.% BMT added sample bridges the nonergodic ferroelectric and ergodic relaxor states, and exhibits a microstructure coexisting P4bm and P4mm symmetries. Our design provides a new route in probing lead-free BNT-based electrocaloric materials apart from the MPB. (C) 2021 Elsevier B.V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
年份: 2021
卷: 889
6 . 2 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:116
JCR分区:1
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