There　is　a　challenge　to　increase　the　application　range　of　chalcogenide　materials　due　to　the　fixed　photoelectric　properties　and　complex　preparation　process.　To　solves　the　problem,　bulk　ceramics　with　different　doping　ratios　should　be　investigated.　Here,　the　influence　of　the　doping　ratio　of　molybdenum　MO　and　Ga　oxide　on　the　composition,　structure,　morphology　and　luminescence　properties　of　bulk　ceramics　is　studied,　the　optimal　doping　ratio　in　this　range　is　determined　by　analysis　of　mass　loss　and　volume　shrinkage.　The　cubic　crystal　structure　is　confirmed　by　X-ray　diffraction　results.　The　results　showed　that　molybdenum　was　successfully　doped　Mo　into　the　matrix　material　is　revealed　by　Raman　spectroscopy.　The　X-ray　fluorescence　is　used　to　study　the　composition　ratio　changes　of　bulk　ceramics　before　and　after　sintering.　The　molecular　structure　model　of　Mo-ZnSe/ZnS　with　different　concentration　is　constructed.　The　X-ray　photoelectron　spectroscopy　shows　the　spin　orbits　of　Zn　2p　and　S　2p,　as　well　as　the　+3　valences　in　terms　of　Mo　and　Ga.　The　optical　performance　is　enhanced　the　light-emitting　band　is　enlarged　to　the　near　infrared　region.　All　the　work　suggest　that　this　new　compound　has　an　improved　micro-structural,　optical　and　electrical　properties.　This　research　can　provide　theoretical　and　experimental　reference　for　the　doping　research　of　chalcogenide　materials　and　new　optoelectronic　devices.