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作者:

Liu, Min (Liu, Min.) | Cui, Haiyuan (Cui, Haiyuan.) | Li, Qingyan (Li, Qingyan.) | Zhu, Peihong (Zhu, Peihong.) | Liu, Weiqiang (Liu, Weiqiang.) (学者:刘卫强) | Lu, Qingmei (Lu, Qingmei.) | Zhang, Dongtao (Zhang, Dongtao.) (学者:张东涛) | Pang, Zaisheng (Pang, Zaisheng.) | Yu, Xi (Yu, Xi.) | Yu, Chunhui (Yu, Chunhui.) | Zha, Shanshun (Zha, Shanshun.) | Liu, Youhao (Liu, Youhao.) | Yi, Xiaofei (Yi, Xiaofei.) | Yue, Ming (Yue, Ming.) (学者:岳明)

收录:

SCIE CSCD

摘要:

The main difficulty for the recovery of Nd-Fe-B bonded magnet wastes is how to completely remove the epoxy resins. In this study, chemical reaction and physical dissolution were combined to remove the epoxy resins by adding ammonia-water and mixed organic solvents. Ammonia-water can react with the epoxy functional group of epoxy resin to generate polyols. Mixed organic solvents of alcohol, dimethyl formamide (DMF), and tetrahydrofuran (THF) can dissolve the generated polyols and residual epoxy resins. Under the optimum processing conditions, the epoxy resins in the waste magnetic powders are substantially removed. The oxygen and carbon contents in the recycled magnetic powder are reduced from 13500 x 10(-6) to 1600 x 10(-6) and from 19500 x 10(-6) to 2100 x 10(-6) with the reduction ratio of 88.1% and 89.2%, respectively. The recycled magnetic powder presents improved magnetic properties with Ms of 1.306 x 10(-1) A.m(2)/g, Mr of 0.926 x 10(-1) A.m(2)/g, Hcj of 1.170 T, and (BH) max of 125.732 kJ/m(3), which reach 99.8%, 99.4%, 95.9%, and 96.9% of the original magnetic powders, respectively. (C) 2021 The Authors. Published by Elsevier B.V.

关键词:

Epoxy resin Nd-Fe-B bonded magnet wastes Open-loop reaction Physical dissolution Rare earths Recycled magnetic powders

作者机构:

  • [ 1 ] [Liu, Min]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Haiyuan]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Qingyan]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhu, Peihong]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Lu, Qingmei]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Dongtao]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 9 ] [Pang, Zaisheng]Ganzhou Fortune Elect Co Ltd, Ganzhou 341000, Peoples R China
  • [ 10 ] [Yu, Xi]Ganzhou Fortune Elect Co Ltd, Ganzhou 341000, Peoples R China
  • [ 11 ] [Yu, Chunhui]Ganzhou Fortune Elect Co Ltd, Ganzhou 341000, Peoples R China
  • [ 12 ] [Zha, Shanshun]Earth Panda Adv Magnet Mat Co, Hefei 231500, Peoples R China
  • [ 13 ] [Liu, Youhao]Earth Panda Adv Magnet Mat Co, Hefei 231500, Peoples R China
  • [ 14 ] [Yi, Xiaofei]Earth Panda Adv Magnet Mat Co, Hefei 231500, Peoples R China

通讯作者信息:

  • 岳明

    [Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF RARE EARTHS

ISSN: 1002-0721

年份: 2021

期: 11

卷: 39

页码: 1396-1401

4 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:7

被引次数:

WoS核心集被引频次: 3

SCOPUS被引频次: 3

ESI高被引论文在榜: 0 展开所有

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