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作者:

Du, Yucheng (Du, Yucheng.) | Zhen, Shuang (Zhen, Shuang.) | Wang, Jinshu (Wang, Jinshu.) | Ma, Yanlong (Ma, Yanlong.) | Wu, Junshu (Wu, Junshu.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE

摘要:

As(V) in aquatic environment has posed a great threat to human beings due to its high mobility and toxicity. Developing economical and efficient adsorbents is vital for the removal of arsenic contamination in wastewater. We herein report the synthesis of FeOOH-MnO2/Sepiolite and Fe2O3-MnO2/Diatomite using the hydrothermal treatment method at 180 degrees C for 12 h with KMnO4, MnCl2, and FeCl3 as metal source and urea as precipitating agent. The FeOOH-MnO2 or Fe2O3-MnO2 composite was in situ grown on the sepiolite or diatomite support, resulting in a significant enhancement in surface area (which was 77.4 and 83.0 m2/g for the supported FeOOHMnO2 and Fe2O3-MnO2 samples, respectively). FeOOH-MnO2/Sepiolite and Fe2O3-MnO2/Diatomite could effectively remove As(V), with the maximal As(V) adsorption capacities at 25 degrees C and pH = 7 being 124.3 and 148.2 mg/g, respectively. Furthermore, both samples exhibited good recycle As(V) adsorption performance. In addition. As(V) adsorption mechanisms of the samples were also discussed. The As(V) adsorption on FeOOHMnO2/Sepiolite and Fe2O3-MnO2/Diatomite obeyed the Freundlich and Langmuir isothermal adsorption models, respectively. Considering their simple synthesis processes and excellent adsorption performance, we are sure that FeOOH-MnO2/Sepiolite and Fe2O3-MnO2/Diatomite are promising adsorbents for arsenic removal from wastewater.

关键词:

Adsorption mechanism Chemical modification Clay minerals As(V) removal Adsorbent

作者机构:

  • [ 1 ] [Du, Yucheng]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zhen, Shuang]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Yanlong]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Wu, Junshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Fac Environm & Life, Sch Environm & Chem Engn,Dept Environm Chem Engn, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Fac Environm & Life, Sch Environm & Chem Engn, Dept Environm Chem Engn,Lab Catalysis Chem & Nano, Beijing 100124, Peoples R China

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来源 :

APPLIED CLAY SCIENCE

ISSN: 0169-1317

年份: 2022

卷: 222

5 . 6

JCR@2022

5 . 6 0 0

JCR@2022

ESI学科: GEOSCIENCES;

ESI高被引阀值:38

JCR分区:1

中科院分区:2

被引次数:

WoS核心集被引频次: 23

SCOPUS被引频次: 26

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

近30日浏览量: 7

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