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作者:

Guo, Wei (Guo, Wei.) | Yue, Junhui (Yue, Junhui.) | Zhao, Qian (Zhao, Qian.) | Zhang, Li (Zhang, Li.) | Lu, Shaoyong (Lu, Shaoyong.)

收录:

Scopus SCIE

摘要:

Removal of steroid hormones from aqueous environment is of prevailing concern because of their adverse impact on organisms. Using biochar derived from biomass as adsorbent to remove pollutants has become more popular due to its low cost, effectiveness, and sustainability. This study evaluated the feasibility of applying corn straw biochar (CSB) and dewatered sludge biochar (DSB) to reduce 17 beta-estradiol (E2) from aquatic solutions by adsorption. The experimental results showed that the adsorption kinetics and isotherm behavior of E2 on the two biochars were well described by the pseudo-second-order (R-2 > 0.93) and Langmuir models (R-2 > 0.97). CSB has higher E2 adsorption capacity than DSB, and the maximum adsorption capacity was 99.8 mg/g obtained from Langmuir model at 298 K, which can be attributed to the higher surface area, porosity, and hydrophobicity of this adsorbent. Higher pH levels (>10.2) decreased the adsorption capacities of biochar for E2, while the ionic strength did not significantly affect the adsorption process. The regeneration ability of CSB was slightly better than that of DSB. The possible adsorption mechanism for E2 on biochar is suggested as pi-pi interactions, H-bonding, and micropores filling. These results indicated that CSB has more potential and application value than DSB on reducing E2 from aqueous solutions when considering economy and removal performance.

关键词:

adsorption 17 beta-estradiol sludge pyrolysis biochar

作者机构:

  • [ 1 ] [Guo, Wei]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Yue, Junhui]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhao, Qian]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Li]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Beijing 100124, Peoples R China
  • [ 5 ] [Lu, Shaoyong]Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing 100012, Peoples R China

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来源 :

MOLECULES

年份: 2022

期: 8

卷: 27

4 . 6

JCR@2022

4 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:53

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 10

SCOPUS被引频次: 10

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 5

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