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作者:

Ji, Changwei (Ji, Changwei.) (学者:纪常伟) | Wang, Zhe (Wang, Zhe.) | Wang, Du (Wang, Du.) | Hou, Ruifeng (Hou, Ruifeng.) | Zhang, Tianyue (Zhang, Tianyue.) | Wang, Shuofeng (Wang, Shuofeng.)

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EI Scopus SCIE

摘要:

Ammonia is considered as a promising hydrogen carrier, which is seen as a reliable carbon-free fuel. Improving the combustion properties of ammonia is the focus of current research. The hydrogen could be dissociated from the ammonia in real applications. For purpose of combustion, partially dissociated ammonia could be combusted directly without using extra hydrogen. Laminar burning velocity is an important combustion parameter, but there are only a few data of partially dissociated ammonia are reported. To fill the data gap, the laminar burning velocity was measured at various equivalence ratios and dissociation degrees of ammonia by the constant pressure spherical flame method in this study. Besides, fifteen kinetic models were compared with experimental data, and the model with the best consistency was obtained. The experimental results show that the laminar burning velocity increases monotonically with the increase of the dissociating degree. When ammonia is completely dissociated, the maximum laminar burning velocity increases from 7.9 cm/s to 228 cm/s, and the equivalence ratio corresponding to the peak value also shifts from 1.1 to 1.6. The laminar burning velocity predicted by the model constructed by Stagni is in best agreement with the experimental data. Moreover, data calculated by the five correlations for predicting laminar burning velocity were compared with the numerical data to verify that whether they are suitable for the mixtures with additional nitrogen. The results show that the correlation based on the activation tem- perature is the most accurate. However, it still has a maximum relative error of +/- 20% within the calculated range. (c) 2021 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.

关键词:

Ammonia Laminar burning velocity Dissociated ammonia Constant pressure combustion

作者机构:

  • [ 1 ] [Ji, Changwei]Beijing Univ Technol, Coll Energy & Power Engn, Beijing Lab New Energy Vehicles, Beijing 100124, Peoples R China
  • [ 2 ] [Ji, Changwei]Beijing Univ Technol, Key Lab Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

ISSN: 0360-3199

年份: 2022

期: 6

卷: 47

页码: 4171-4184

7 . 2

JCR@2022

7 . 2 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:49

JCR分区:1

中科院分区:2

被引次数:

WoS核心集被引频次: 61

SCOPUS被引频次: 75

ESI高被引论文在榜: 0 展开所有

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