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作者:

Sun, Guoqiang (Sun, Guoqiang.) | Zhu, Xiaobin (Zhu, Xiaobin.) | Zhang, Qiyi (Zhang, Qiyi.) | Yan, Chuanqi (Yan, Chuanqi.) | Ning, Weidong (Ning, Weidong.) | Wang, Tao (Wang, Tao.)

收录:

EI Scopus SCIE

摘要:

High viscosity modified asphalt (HVMA) was the core material to build ecological permeable pavement, while it was prone to aging, which limited its applications for urban sustainability. This study focused on the oxidation and polymer degradation characteristics of the high-content styrene-butadiene-styrene modified asphalt, high-viscosity composite particle modified asphalt and high-elastic modified asphalt under the simulated aging environments of thermal oxidation and weather. Gel permeation chromatography results showed that the increase percent of large molecular size percent and the decrease percent of polymer weight could characterize the oxidation degree and polymer degradation degree, respectively. The degrees of oxidation and polymer degradation in all HVMAs increased synchronously with aging, and reached the highest after the weather aging. The polymer molecular distribution of HVMA would become more uniform with aging from the proposed ratio of polymer weight to polymer content. Dynamic shear rheometer tests reflected that there existed the dual effects of coupling and parallelism during aging of HVMA, i.e. the oxidation-induced hardening effect and degradation-induced softening effect. Furthermore, the change percent of rheological indicators was proposed as the net aging degree. Considering the rheological properties of aged HVMA were the coupling results of dual effects, the net aging degree could represent the oxidation dominance degree or polymer degradation dominance degree of HVMA. Due to the differences of dual effects and polymer molecular distribution, various HVMAs showed the totally different net aging degree ranking, depending on the aging states and rheological indicators. Notably, the high-elastic modified asphalt showed the greatest aging resistance at all aging states as a result of its weak dual effects and most uniform polymer molecular distribution.

关键词:

Polymer degradation Dual effects High viscosity modi fied asphalts Weather aging Polymer distribution Oxidation

作者机构:

  • [ 1 ] [Sun, Guoqiang]Beijing Univ Technol, Beijing Key Lab Traff Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Qiyi]Beijing Univ Technol, Beijing Key Lab Traff Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Ning, Weidong]Beijing Univ Technol, Beijing Key Lab Traff Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhu, Xiaobin]State Key Lab High Performance Civil Engn Mat, Nanjing 210008, Peoples R China
  • [ 5 ] [Yan, Chuanqi]Southwest Jiaotong Univ, Key Lab Rd Engn Sichuan Prov, Chengdu 610031, Peoples R China
  • [ 6 ] [Wang, Tao]Beijing Jiaotong Univ, Sch Civil Engn, Dept Highway & Railway Engn, Beijing 100044, Peoples R China

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来源 :

SCIENCE OF THE TOTAL ENVIRONMENT

ISSN: 0048-9697

年份: 2021

卷: 813

9 . 8 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:94

JCR分区:1

被引次数:

WoS核心集被引频次: 36

SCOPUS被引频次: 40

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 6

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