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摘要:
The nickel, cobalt, manganese and lithium metals in the ternary cathode material of scrapped power battery were recovered by high temperature hydrogen reduction and hydrometallurgical method, and the recovery mechanism and process were studied. The results show that the Li in the layered Ni-Co-Mn oxide migrates to the surface and becomes LiOH, LiOHH2O and a small amount of Li2CO3 after high temperature reduction. The Co2+, Ni3+ and Mn4+ are reduced to Co0, Ni0 and MnO, respectively. And the surface phases of the reduced materials are referred as Ni(OH)2, Co(OH)2 and MnO after Li leaching. The Li2CO3 with 99.5% in purity is obtained from the water leaching, acid washing, and precipitation processes of LiOH, LiOHH2O and a small amount of Li2CO3, which realizes the separation of Li from Co-Ni-Mn. After the sulfuric acid leaching of the reduced Ni, Co and MnO, the leaching rates of Ni, Co and Mn are 96.88%, 97.23% and 99.78%, respectively. The precipitation and separation rate of Mn is 98.46% after the oxidizing precipitation and extraction separation of the leached solution, and the impurity contents in CoCl2 and NiCl2 solutions are less than 10 mg/L after the extraction separation. © 2020, Science Press. All right reserved.
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Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
年份: 2020
期: 6
卷: 30
页码: 1415-1426