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摘要:
Germanium (Ge)-based materials can serve as promising anode candidates for high-energy lithium ion batteries (LIBs). However, the rapid capacity decay caused by huge volume expansion severely retards their application. Herein, we report a facile and controllable synthesis of Ge nanowire anode materials through molten salt electrolysis. The optimal Ge nanowires can deliver a capacity of 1058.9 mAh g(-1) at 300 mA g(-1) and a capacity above 602.5 mAh g(-1) at 3000 mA g(-1) for 900 cycles. By in situ transmission electron microscopy and in situ X-ray diffraction, the multiple-step phase transformation and good structural reversibility of the Ge nanowires during charge/discharge are elucidated. When coupled with a lithium-rich Li(1.2)Mn(0.56)7Ni(0.167)Co(0.06)7O(2) cathode in a full battery, the Ge nanowire anode leads to a relatively stable capacity with a retention of 84.5% over 100 cycles. This research highlights the significance of molten-salt electrolysis for the synthesis of alloy-type anode materials toward high-energy LIBs.
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来源 :
ACS NANO
ISSN: 1936-0851
年份: 2022
期: 9
卷: 16
页码: 14402-14411
1 7 . 1
JCR@2022
1 7 . 1 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:53
JCR分区:1
中科院分区:1
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