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作者:

Zhu, Yuhan (Zhu, Yuhan.) | Zhao, Qian (Zhao, Qian.) | Li, Dongyue (Li, Dongyue.) | Li, Jun (Li, Jun.) | Guo, Wei (Guo, Wei.)

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摘要:

Recycling of phosphorus (P) from pyrolysis sewage sludge is a good methodology to deal with the deficit of P resources and safely dispose the sewage sludge. However, it is essential to determine the type of sludge in sewage treatment plants (STPs) along with the most appropriate pyrolysis temperature. These factors affect the form and bioavailability of recoverable P. Thus, four kinds of sludge in a typical STP were selected, and three pyrolysis temperatures including 300, 500, and 700 ?C were set to find a suitable strategy for P recovery. The results indicated that with increasing pyrolysis temperature, more organic phosphorus (OP) was transformed into inorganic phosphorus (IP) and more non-apatite inorganic phosphorus (NAIP) was converted to apatite phos-phorus (AP, mainly Ca-3(PO4)(2), Ca(H2PO4)(2), Mg-3(PO4)(2), Ca3Mg3(PO4)(4), and Ca-5(PO4)3OH). Compared to other sludges, dewatered cake sludge (CS) pyrolyzed at 700 ?C had the highest AP content, about 1.1-3.6 times that in other pyrolysis products, and the highest Ca-5(PO4)(3)OH content containing 35.8% of total phosphorus (TP). The contents of P-2% citric acid (CA) and neutral ammonium citrate (NAC) in CS obtained by pyrolysis at 500 ?C reached 45.6 and 49.6 mg/g, respectively, which were 1.1-3.0 and 1.1-2.8 times that of P-CA and P-NAC in other sludges and their biochars, respectively. Moreover, the diethylenetriaminepentaacetic acid extraction analysis indicated that the good stability of heavy metals in CS-derived biochar was better than that in the feedstock. Hence, to ensure the efficiency and safety of P, CS is used as raw material in STPs to recover P re-sources. CS-500 can be used as the direct P source of land owing to the highest concentration of bioavailable P (P -CA and P-NAC), while CS-700 can be used to represent a slow-release P fertilizer because it contains the highest concentration of AP.

关键词:

Bioavailability Pyrolysis biochar Recovery Sewage sludge sources Phosphorus species

作者机构:

  • [ 1 ] [Zhu, Yuhan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing, Peoples R China
  • [ 2 ] [Zhao, Qian]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing, Peoples R China
  • [ 3 ] [Li, Dongyue]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing, Peoples R China
  • [ 4 ] [Li, Jun]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing, Peoples R China
  • [ 5 ] [Guo, Wei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing, Peoples R China
  • [ 6 ] [Li, Jun]Beijing Univ Technol, Pingleyuan 100, Beijing 100124, Chaoyang, Peoples R China
  • [ 7 ] [Guo, Wei]Beijing Univ Technol, Pingleyuan 100, Beijing 100124, Chaoyang, Peoples R China

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来源 :

JOURNAL OF CLEANER PRODUCTION

ISSN: 0959-6526

年份: 2022

卷: 372

1 1 . 1

JCR@2022

1 1 . 1 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:49

JCR分区:1

中科院分区:1

被引次数:

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SCOPUS被引频次: 42

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