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作者:

Yu, Rui (Yu, Rui.) | Yang, Yanling (Yang, Yanling.) | Zhou, Zhiwei (Zhou, Zhiwei.) | Li, Xing (Li, Xing.) | Gao, Jingfeng (Gao, Jingfeng.) | Wang, Nan (Wang, Nan.) | Li, Jiaqi (Li, Jiaqi.) | Liu, Yongwang (Liu, Yongwang.)

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EI Scopus SCIE

摘要:

In this work, a novel ternary heterojunction composite with bismuth oxide (Bi2O3), titanium dioxide (TiO2) and reduced graphene oxide (rGO) was produced via a one-step hydrothermal process. The prepared Bi2O3/rGO/ TiO2 (BRGT) composite possessed a strong visible-light responsiveness and a high separation efficiency of photogenerated carriers, with a specific surface area of 133.1 m(2)/g. The optimal degradation performance towards tetracycline (94.3% removal) was obtained by BRGT-10 with Bi/Ti molar ratio of 10% and mass ratio of graphene oxide/Ti of 5% following conditions of 0.1 g/L BRGT-10 at pH of 6.7. The degradation rate of tetra-cycline by BRGT was 4.5, 3.8, 1.4, and 1.28 times that of TiO2, TiO2/rGO, Bi2O3/TiO2, and Bi2O3/TiO2@rGO, respectively. O-center dot(2)- radicals and holes play the dominant roles in the photodegradation of tetracycline. Based on density function theory calculation and liquid chromatography-mass spectrometry identification of intermediates, the degradation pathways of tetracycline were mostly attributed to the breakage of carbon-carbon double bonds, nitrogen-carbon bonds and rearrangement of hydroxyl groups, and the decreased toxicity of the formed intermediates was evaluated. The BRGT-10 composite owned optimal reusability and applicability. This study explores a facile synthesis process of ternary heterojunction composite and provides insights into photo-degradation mechanism of refractory organics from water under visible-light.

关键词:

Reduced graphene oxide Ternary heterojunction Degradation pathway Photogenerated carriers

作者机构:

  • [ 1 ] [Yu, Rui]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construction, Beijing 100124, Peoples R China
  • [ 2 ] [Yang, Yanling]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construction, Beijing 100124, Peoples R China
  • [ 3 ] [Zhou, Zhiwei]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construction, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Xing]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construction, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Jiaqi]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construction, Beijing 100124, Peoples R China
  • [ 6 ] [Zhou, Zhiwei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing 100124, Peoples R China
  • [ 7 ] [Gao, Jingfeng]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Beijing 100124, Peoples R China
  • [ 8 ] [Wang, Nan]Tsinghua Univ, Ctr Water & Ecol, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Cont, Beijing 100084, Peoples R China
  • [ 9 ] [Liu, Yongwang]China Architecture Design & Res Grp, Beijing 100044, Peoples R China
  • [ 10 ] [Zhou, Zhiwei]Beijing Univ Technol, 100 Xi Da Wang Rd, Beijing 100124, Peoples R China

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来源 :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

年份: 2022

卷: 299

8 . 6

JCR@2022

8 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:53

JCR分区:1

中科院分区:1

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SCOPUS被引频次: 23

ESI高被引论文在榜: 0 展开所有

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