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作者:

Wang, Changlong (Wang, Changlong.) | Wu, Yufeng (Wu, Yufeng.) | Bodach, Alexander (Bodach, Alexander.) | Krebs, Moritz Lukas (Krebs, Moritz Lukas.) | Schuhmann, Wolfgang (Schuhmann, Wolfgang.) | Schueth, Ferdi (Schueth, Ferdi.)

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EI Scopus SCIE

摘要:

Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi-step reaction requiring a high overpotential. At the same time,it does not add value-the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high-performance electrode based on earth-abundant elements synthesized in the presence of H2O2, which is able to sustain current densities of close to 1 A cm(-2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis.

关键词:

FDCA NiFe Electrode H2O2 High Current Density Anodic Oxidation

作者机构:

  • [ 1 ] [Wang, Changlong]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 2 ] [Bodach, Alexander]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 3 ] [Krebs, Moritz Lukas]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 4 ] [Schueth, Ferdi]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 5 ] [Wang, Changlong]Beijing Univ Technol, Inst Circular Econ, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Wu, Yufeng]Beijing Univ Technol, Inst Circular Econ, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Schuhmann, Wolfgang]Ruhr Univ Bochum, Analyt Chem Ctr Electrochem Sci CES, Univ Str 150, D-44780 Bochum, Germany
  • [ 8 ] [Schuhmann, Wolfgang]Ruhr Univ Bochum, Fac Chem & Biochem, Univ Str 150, D-44780 Bochum, Germany

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来源 :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

年份: 2022

期: 7

卷: 62

1 6 . 6

JCR@2022

1 6 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:53

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 35

SCOPUS被引频次: 57

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 3

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