The　organoselenium-catalyzed　amination　of　alkenes　is　a　promising　way　to　construct　functionalized　amines.　However,　the　use　of　chemical　oxidants　and　the　unavoidable　formation　of　allylic　amine　or　enamine　are　the　two　main　limitations　of　these　methodologies.　Against　this　background,　we　herein　report　an　electro-selenocatalytic　regime　for　the　hydroazolylation　of　alkenes　with　azoles　under　external　oxidant-free　conditions　with　low　catalyst　loadings.　Moreover,　this　protocol　enables　the　generation　of　amines　without　vinyl　substituents.