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作者:

Ma, Jiangping (Ma, Jiangping.) | Xiong, Xin (Xiong, Xin.) | Ban, Chaogang (Ban, Chaogang.) | Wang, Kaiwen (Wang, Kaiwen.) | Dai, Ji-Yan (Dai, Ji-Yan.) | Zhou, Xiaoyuan (Zhou, Xiaoyuan.)

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摘要:

Ultrasound-stimulated piezo-electrocatalysis has been studied for a period; however, the mechanism is still unclear mainly due to the coexistence with other multiple effects like sonocatalysis, which was usually ignored. In this work, with the non-piezoelectric H2Ti3O7 nanowires following the same experimental process in piezo-electrocatalysis, the sonocatalytic reduction performance of CO2 is investigated. By applying vibration under the excitation of ultrasound with various frequencies and powers, it is found that CO is the ultimate product with a selectivity of 100%, and the optimal CO yield of 8.3 mu mol g(-1) h(-1) is achieved with the addition of sacrificial agents. The H2Ti3O7 catalysts are also found to present a good recycling utilization ability. This work indicates that the sonocatalysis effect may exist in the piezo-electrocatalytic process using the ultrasonic excitation, which is suggested to be taken into consideration when exploring the mechanism of piezo-electrocatalysis in the future. Published under an exclusive license by AIP Publishing.

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作者机构:

  • [ 1 ] [Ma, Jiangping]Chongqing Univ, Coll Phys, Ctr Quantum Mat & Devices, Chongqing 401331, Peoples R China
  • [ 2 ] [Xiong, Xin]Chongqing Univ, Coll Phys, Ctr Quantum Mat & Devices, Chongqing 401331, Peoples R China
  • [ 3 ] [Ban, Chaogang]Chongqing Univ, Coll Phys, Ctr Quantum Mat & Devices, Chongqing 401331, Peoples R China
  • [ 4 ] [Zhou, Xiaoyuan]Chongqing Univ, Coll Phys, Ctr Quantum Mat & Devices, Chongqing 401331, Peoples R China
  • [ 5 ] [Wang, Kaiwen]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Ji-Yan]Hong Kong Polytech Univ, Dept Appl Phys, Hong Kong 999077, Peoples R China
  • [ 7 ] [Zhou, Xiaoyuan]Chongqing Univ, State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 401331, Peoples R China

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来源 :

APPLIED PHYSICS LETTERS

ISSN: 0003-6951

年份: 2022

期: 26

卷: 121

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JCR@2022

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JCR@2022

ESI学科: PHYSICS;

ESI高被引阀值:41

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 16

SCOPUS被引频次: 17

ESI高被引论文在榜: 0 展开所有

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