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作者:

Zhang, Xiao (Zhang, Xiao.) | De Volder, Michael (De Volder, Michael.) | Zhou, Wenbin (Zhou, Wenbin.) | Issman, Liron (Issman, Liron.) | Wei, Xiaojun (Wei, Xiaojun.) | Kaniyoor, Adarsh (Kaniyoor, Adarsh.) | Portas, Jeronimo Terrones (Portas, Jeronimo Terrones.) | Smail, Fiona (Smail, Fiona.) | Wang, Zibo (Wang, Zibo.) | Wang, Yanchun (Wang, Yanchun.) | Liu, Huaping (Liu, Huaping.) | Zhou, Weiya (Zhou, Weiya.) | Elliott, James (Elliott, James.) | Xie, Sishen (Xie, Sishen.) | Boies, Adam (Boies, Adam.)

收录:

SCIE

摘要:

Although individual carbon nanotubes (CNTs) are superior to polymer chains, the mechanical and thermal properties of CNT fibers (CNTFs) remain inferior to synthetic fibers because of the failure of embedding CNTs effectively in superstructures. Conventional techniques resulted in a mild improvement of target properties while degrading others. Here, a double-drawing technique is developed to rearrange the constituent CNTs. Consequently, the mechanical and thermal properties of the resulting CNTFs can simultaneously reach their highest performances with specific strength ~3.30 N tex(-1) (4.60 GPa), work of rupture ~70 J g(-1), and thermal conductivity ~354 W m(-1) K-1 despite starting from low-crystallinity materials (IG:ID ~ 5). The processed CNTFs are more versatile than comparable carbon fiber, Zylon and Dyneema. On the basis of evidence of load transfer efficiency on individual CNTs measured with in situ stretching Raman, we find that the main contributors to property enhancements are the increasing of the effective tube contribution.

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作者机构:

  • [ 1 ] [Zhang, Xiao]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 2 ] [Wei, Xiaojun]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 3 ] [Wang, Zibo]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 4 ] [Wang, Yanchun]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 5 ] [Liu, Huaping]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 6 ] [Zhou, Weiya]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 7 ] [Xie, Sishen]Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
  • [ 8 ] [Zhang, Xiao]Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
  • [ 9 ] [De Volder, Michael]Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
  • [ 10 ] [Issman, Liron]Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
  • [ 11 ] [Smail, Fiona]Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
  • [ 12 ] [Boies, Adam]Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
  • [ 13 ] [Zhou, Wenbin]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 14 ] [Kaniyoor, Adarsh]Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England
  • [ 15 ] [Portas, Jeronimo Terrones]Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England
  • [ 16 ] [Elliott, James]Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England

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来源 :

SCIENCE ADVANCES

ISSN: 2375-2548

年份: 2022

期: 50

卷: 8

1 3 . 6

JCR@2022

1 3 . 6 0 0

JCR@2022

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 19

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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