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Author:

Li, Jiaqiang (Li, Jiaqiang.) | Wen, Yeye (Wen, Yeye.) | Xiao, Zhihua (Xiao, Zhihua.) | Wang, Shijun (Wang, Shijun.) | Zhong, Lixiang (Zhong, Lixiang.) | Li, Tao (Li, Tao.) | Jiao, Kun (Jiao, Kun.) | Li, Lanying (Li, Lanying.) | Luo, Jiajun (Luo, Jiajun.) | Gao, Zhenfei (Gao, Zhenfei.) | Li, Shuzhou (Li, Shuzhou.) | Zhang, Zhong (Zhang, Zhong.) | Zhang, Jin (Zhang, Jin.)

Indexed by:

EI Scopus SCIE

Abstract:

Poly(p-phenylene-benzimidazole-terephthalamide) (PBIA) fibers, a kind of heterocyclic aramid fibers, possess extraordinary mechanical properties and advanced applications in aerospace, military protection, and other civilian areas. However, harsh application scenarios are putting forward even stringent requirements for the mechanical performances and environmental compatibility of PBIA fibers. Strengthening lateral interactions between polymer chains are approachable methods but ongoing challenges to obtain PBIA fibers with high-performance. This work develops a novel holey reduced-graphene-oxide (HrGO)/PBIA composite fiber with a scaffolded structure, in which the HrGO plays a role of clamp to effectively band plentiful PBIA chains through the in-plane holes. A small amount of HrGO (0.075 wt%) is able to improve the tensile strength and Young's modulus of HrGO/PBIA fibers by 11.5% and 8.3%, respectively. The small amount of well dispersed HrGO improves the crystallinity and serves as the topological constraint that enhances the lateral interaction of the PBIA chains, which is unveiled by the wide-angle X-ray scattering and the coarse-grained molecular dynamics simulations. In addition, the favorable compatibility of HrGO/PBIA fibers in complex application scenarios is demonstrated by the dynamic and cyclic-loading measurements.

Keyword:

lateral interactions scaffolded structures heterocyclic aramid fibers mechanical properties holey graphene

Author Community:

  • [ 1 ] [Li, Jiaqiang]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 2 ] [Wen, Yeye]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 3 ] [Xiao, Zhihua]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 4 ] [Jiao, Kun]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 5 ] [Luo, Jiajun]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 6 ] [Zhang, Jin]Peking Univ, Coll Chem & Mol Engn, Ctr Nano Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 7 ] [Li, Jiaqiang]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 8 ] [Wen, Yeye]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 9 ] [Xiao, Zhihua]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 10 ] [Li, Tao]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 11 ] [Jiao, Kun]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 12 ] [Luo, Jiajun]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 13 ] [Gao, Zhenfei]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 14 ] [Zhang, Jin]Beijing Graphene Inst BGI, Div Graphene Fiber Technol, Beijing 100095, Peoples R China
  • [ 15 ] [Li, Jiaqiang]King Abdullah Univ Sci & Technol, Adv Membranes & Porous Mat Ctr, Phys Sci & Engn Div, Thuwal 239556900, Saudi Arabia
  • [ 16 ] [Wang, Shijun]Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
  • [ 17 ] [Zhang, Zhong]Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
  • [ 18 ] [Zhong, Lixiang]Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
  • [ 19 ] [Li, Shuzhou]Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
  • [ 20 ] [Li, Tao]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100021, Peoples R China
  • [ 21 ] [Jiao, Kun]Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China
  • [ 22 ] [Li, Lanying]Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China
  • [ 23 ] [Zhang, Jin]Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China
  • [ 24 ] [Li, Lanying]China Bluestar Chengrand Chem Co Ltd, Chengdu 610041, Peoples R China
  • [ 25 ] [Zhang, Zhong]Univ Sci & Technol China, Dept Modern Mech, CAS Key Lab Mech Behav & Design Mat, Hefei 230026, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2022

Issue: 42

Volume: 32

1 9 . 0

JCR@2022

1 9 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 25

SCOPUS Cited Count: 28

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Affiliated Colleges:

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