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作者:

Shaheen, Kausar (Shaheen, Kausar.) | Suo, Hongli (Suo, Hongli.) (学者:索红莉) | Arshad, Tofail (Arshad, Tofail.) | Shah, Zarbad (Shah, Zarbad.) | Khan, Shahid Ali (Khan, Shahid Ali.) | Khan, Sher Bahadar (Khan, Sher Bahadar.) | Khan, Muhammad Naeem (Khan, Muhammad Naeem.) | Liu, Min (Liu, Min.) | Ma, Lin (Ma, Lin.) | Cui, Jin (Cui, Jin.) | Ji, Yao Tang (Ji, Yao Tang.) | Wang, Yi (Wang, Yi.)

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SCIE

摘要:

Metal oxides based on Cu-Sr, Sr-Cd and Cd-Cu were synthesized by mild and cost effective co-precipitation method. XRD and SEM were utilized in order to investigate the phase structure, composition and morphology of as synthesized metal oxides. Crystallite size calculated through XRD was found to be 40.36, 49.97 and 82.62 nm for Cu-Sr, Sr-Cd and Cd-Cu metal oxides whereas, SEM indicated particle size ranged from (44-88)nm. Elemental contents, functional groups and thermal stability of these metal oxides were determined via XPS, FTIR and TGA. Band gap energies were measured as 1.57, 1.64 and 1.61 eV while, BET analysis indicated surface area similar to 9.86, 1.99 and 49.78m(2)/g with total pore volume/average aperture size similar to 0.0348 ml/g/1.0934 nm, 0.0127 ml/g/0.1101 nm and 0.1080 ml/g/0.9254 nm for Cu-Sr, Sr-Cd, and Cd-Cu metal oxides respectively. These metal oxides were used as photocatalysts for the degradation of MB and MO dyes under solar light irradiation showing higher catalytic activity with 86, 78 and 67 % degradation for MB dye, while 80, 50 and 69 % degradation was observed for MO dye within total time of 180 min. Effect of various operational parameters such as catalyst loading, pH, and various scavengers was evaluated in detail. Morever, in-situ investigations were also carried out in order to determine the active species and hence the mechanism for catalytic reactions. These results for dye detoxification and corresponding reaction mechanism suggested the synthesized metal oxides as promising candidates for real toxic water wastes cleanup applications.

关键词:

Metal oxides Methylene blue Methyl orange Photocatalysts Solar light

作者机构:

  • [ 1 ] [Shaheen, Kausar]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Suo, Hongli]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Min]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Lin]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Cui, Jin]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Ji, Yao Tang]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Yi]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Shaheen, Kausar]Univ Peshawar, Dept Phys, Peshawar 25120, Khyber Pakhtunk, Pakistan
  • [ 9 ] [Shaheen, Kausar]Univ Peshawar, Jinnah Coll Women, Dept Phys, Peshawar 25120, Khyber Pakhtunk, Pakistan
  • [ 10 ] [Arshad, Tofail]Bacha Khan Univ Charsadda, Dept Chem, Charsadda 24420, Khyber Pakhtunk, Pakistan
  • [ 11 ] [Shah, Zarbad]Bacha Khan Univ Charsadda, Dept Chem, Charsadda 24420, Khyber Pakhtunk, Pakistan
  • [ 12 ] [Khan, Muhammad Naeem]Bacha Khan Univ Charsadda, Dept Chem, Charsadda 24420, Khyber Pakhtunk, Pakistan
  • [ 13 ] [Khan, Shahid Ali]Univ Swabi, Dept Chem, Anbar 23561, Khyber Pakhtunk, Pakistan
  • [ 14 ] [Khan, Sher Bahadar]King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia
  • [ 15 ] [Khan, Sher Bahadar]King Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah 21589, Saudi Arabia

通讯作者信息:

  • 索红莉

    [Shah, Zarbad]Bacha Khan Univ Charsadda, Dept Chem, Charsadda 24420, Khyber Pakhtunk, Pakistan;;[Suo, Hongli]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF WATER PROCESS ENGINEERING

ISSN: 2214-7144

年份: 2020

卷: 34

7 . 0 0 0

JCR@2022

JCR分区:1

被引次数:

WoS核心集被引频次: 16

SCOPUS被引频次: 21

ESI高被引论文在榜: 0 展开所有

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