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作者:

Liang, Quanming (Liang, Quanming.) | Li, Jian (Li, Jian.) | He, Hong (He, Hong.) (学者:何洪) | Yue, Tao (Yue, Tao.) | Tong, Li (Tong, Li.)

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摘要:

F-V2O5-WO3/TiO2 catalysts were prepared by the impregnation method. As the content of F ions increased from 0.00 to 0.35 wt.%, the NO conversion of F-V2O5-WO3/TiO2 catalysts initially increased and then decreased. The 0.2F-V2O5-WO3/TiO2 catalyst (0.2 wt.% F ion) exhibited the best denitration (De-NOx) performance, with more than 95% NO conversion in the temperature range 160-360 degrees C, and 99.0% N-2 selectivity between 110 and 280 degrees C. The addition of an appropriate amount of F ions eroded the surface morphology of the catalyst and reduced its grain size, thus enhancing the NO conversion at low temperature as well as the sulfur and water resistance of the V2O5-WO3/TiO2 catalyst. After selective catalytic reduction (SCR) reaction in a gas flow containing SO2 and H2O, the number of NH3 adsorption sites, active component content, specific surface area and pore volume decreased to different degrees. Ammonium sulfate species deposited on the catalyst surface, which blocked part of the active sites and reduced the NO conversion performance of the catalyst. On-line thermal regeneration could not completely recover the catalyst activity, although it prolonged the cumulative life of the catalyst. In addition, a mechanism for the effects of SO2 and H2O on catalyst NO conversion was proposed. (C) 2020 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

关键词:

On-line thermal regeneration F ions Sulfur resistance Low temperature selective catalytic reduction

作者机构:

  • [ 1 ] [Liang, Quanming]Beijing Acad Sci & Technol, Beijing Municipal Inst Lab Protect, Beijing 100054, Peoples R China
  • [ 2 ] [Yue, Tao]Beijing Acad Sci & Technol, Beijing Municipal Inst Lab Protect, Beijing 100054, Peoples R China
  • [ 3 ] [Tong, Li]Beijing Acad Sci & Technol, Beijing Municipal Inst Lab Protect, Beijing 100054, Peoples R China
  • [ 4 ] [Liang, Quanming]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [He, Hong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

通讯作者信息:

  • [Yue, Tao]Beijing Acad Sci & Technol, Beijing Municipal Inst Lab Protect, Beijing 100054, Peoples R China;;[Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF ENVIRONMENTAL SCIENCES

ISSN: 1001-0742

年份: 2020

卷: 90

页码: 253-261

6 . 9 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:138

被引次数:

WoS核心集被引频次: 27

SCOPUS被引频次: 28

ESI高被引论文在榜: 0 展开所有

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