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作者:

Yang, Jun (Yang, Jun.) | Xue, Yutong (Xue, Yutong.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Jiang, Xiyun (Jiang, Xiyun.) | Chen, Huan (Chen, Huan.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE PubMed CSCD

摘要:

Mesoporous Co3O4 (meso-Co3O4)-supported Pt (0.53 wt.% Pt/meso-Co3O4) was synthesized via the KIT-6-templating and polyvinyl alcohol (PVA)-assisted reduction routes. Mesoporous CoO (meso-CoO) was fabricated through in situ reduction of meso-Co3O4 with glycerol, and the 0.18-0.69 wt.% Pt/meso-CoO samples were generated by the PVA-assisted reduction method. Meso-Co3O4 and meso-CoO were of cubic crystal structure and the Pt nanoparticles (NPs) with a uniform size of ca. 2 nm were well distributed on the meso-Co3O4 or meso-CoO surface. The 0.56 wt% Pt/meso-CoO (0.56Pt/meso-CoO) sample performed the best in benzene combustion (T-50% = 156 degrees C and T-90% = 186 degrees C at a space velocity of 80,000 mL/(g h)). Introducing water vapor or CO2 with a certain concentration led to partial deactivation of 0.56 Pt/meso-CoO and such a deactivation was reversible. We think that the superior catalytic activity of 0.56 Pt/meso-CoO was intimately related to its good oxygen activation and benzene adsorption ability. (C) 2019 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

关键词:

Oxygen activation Benzene combustion Mesoporous cobalt oxide Benzene adsorption Supported Pt catalyst

作者机构:

  • [ 1 ] [Yang, Jun]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Yuxi]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 4 ] [Jiang, Xiyun]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 5 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 6 ] [Xue, Yutong]Beijing Guangqumen Middle Sch, Beijing 100062, Peoples R China
  • [ 7 ] [Chen, Huan]Beijing Guangqumen Middle Sch, Beijing 100062, Peoples R China

通讯作者信息:

  • 戴洪兴

    [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn,Lab Catalysis Chem &, Dept Chem & Chem Engn,Key Lab Adv Funct Mat,Educ, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF ENVIRONMENTAL SCIENCES

ISSN: 1001-0742

年份: 2020

卷: 90

页码: 170-179

6 . 9 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:138

被引次数:

WoS核心集被引频次: 13

SCOPUS被引频次: 13

ESI高被引论文在榜: 0 展开所有

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