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Lithium rare metal is the core of the lithium ion battery. Lithium ions in the form of lithium metal oxide with different spatial structure (layered, olivine and spinel) constitutes cathode material of lithium ion batteries. Lithium salts make up the bulk of the electrolyte. Lithium metal forms the anode of battery. The processes of lithium ions insertion and extraction between the cathode and anode through electrolyte can realize the energy conversion between chemical energy and electric energy. The cathode materials composed of lithium elements with different structures have their own advantages in the five core indicators of battery including cost, energy, power, life and safety. Different kinds of lithium salts have their own advantages in thermal stability, ion mobility and cost. Side reactions between anode and electrolyte are one of the major problems for lithium metal. Herein, this paper summarized the reserves, distribution and application fields of lithium resources. Based on the research status at home and abroad, a comprehensive review was given on the characteristics, advantages and existing problems of different types of lithium metal oxide. The development, advantages, existing problems and corresponding solutions of the lithium metal as the batteries anodes were also summarized. The characteristics of different lithium salts summed up as well. Meanwhile, the development direction of lithium ion battery was analyzed. The importance of lithium metal to the development for future science and technology was predicted. © Editorial Office of Chinese Journal of Rare Metals. All right reserved.
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