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Author:

Zhang, Xiao (Zhang, Xiao.) | De Volder, Michael (De Volder, Michael.) | Zhou, Wenbin (Zhou, Wenbin.) | Issman, Liron (Issman, Liron.) | Wei, Xiaojun (Wei, Xiaojun.) | Kaniyoor, Adarsh (Kaniyoor, Adarsh.) | Portas, Jeronimo Terrones (Portas, Jeronimo Terrones.) | Smail, Fiona (Smail, Fiona.) | Wang, Zibo (Wang, Zibo.) | Wang, Yanchun (Wang, Yanchun.) | Liu, Huaping (Liu, Huaping.) | Zhou, Weiya (Zhou, Weiya.) | Elliott, James (Elliott, James.) | Xie, Sishen (Xie, Sishen.) | Boies, Adam (Boies, Adam.)

Indexed by:

EI Scopus

Abstract:

Although individual carbon nanotubes (CNTs) are superior to polymer chains, the mechanical and thermal properties of CNT fibers (CNTFs) remain inferior to synthetic fibers because of the failure of embedding CNTs effectively in superstructures. Conventional techniques resulted in a mild improvement of target properties while degrading others. Here, a double-drawing technique is developed to rearrange the constituent CNTs. Consequently, the mechanical and thermal properties of the resulting CNTFs can simultaneously reach their highest performances with specific strength ∼3.30 N tex-1 (4.60 GPa), work of rupture ∼70 J g-1, and thermal conductivity ∼354 W m-1 K-1 despite starting from low-crystallinity materials (IG:ID ∼ 5). The processed CNTFs are more versatile than comparable carbon fiber, Zylon and Dyneema. On the basis of evidence of load transfer efficiency on individual CNTs measured with in situ stretching Raman, we find that the main contributors to property enhancements are the increasing of the effective tube contribution. © 2022 The Authors.

Keyword:

Carbon fibers Carbon nanotubes Thermal conductivity Crystallinity

Author Community:

  • [ 1 ] [Zhang, Xiao]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 2 ] [Zhang, Xiao]Department of Engineering, University of Cambridge, Cambridge; CB2 1PZ, United Kingdom
  • [ 3 ] [De Volder, Michael]Department of Engineering, University of Cambridge, Cambridge; CB2 1PZ, United Kingdom
  • [ 4 ] [Zhou, Wenbin]MOE Key Laboratory of Enhanced Heat Transfer and Energy Conservation, Beijing Key Laboratory of Heat Transfer and Energy Conversion, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Issman, Liron]Department of Engineering, University of Cambridge, Cambridge; CB2 1PZ, United Kingdom
  • [ 6 ] [Wei, Xiaojun]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 7 ] [Kaniyoor, Adarsh]Department of Materials Science and Metallurgy, University of Cambridge, Cambridge; CB3 0FS, United Kingdom
  • [ 8 ] [Portas, Jeronimo Terrones]Department of Materials Science and Metallurgy, University of Cambridge, Cambridge; CB3 0FS, United Kingdom
  • [ 9 ] [Smail, Fiona]Department of Engineering, University of Cambridge, Cambridge; CB2 1PZ, United Kingdom
  • [ 10 ] [Wang, Zibo]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 11 ] [Wang, Yanchun]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 12 ] [Liu, Huaping]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 13 ] [Zhou, Weiya]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 14 ] [Elliott, James]Department of Materials Science and Metallurgy, University of Cambridge, Cambridge; CB3 0FS, United Kingdom
  • [ 15 ] [Xie, Sishen]Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing; 100190, China
  • [ 16 ] [Boies, Adam]Department of Engineering, University of Cambridge, Cambridge; CB2 1PZ, United Kingdom

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Source :

Science Advances

Year: 2022

Issue: 50

Volume: 8

1 3 . 6

JCR@2022

1 3 . 6 0 0

JCR@2022

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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