Recovery　of　butanol　is　a　potential　biofuel　production　process,　which　can　be　achieved　through　membrane　separation　technology.　In　this　study,　Zeolitic　Imidazolate　Framework-8　(ZIF-8)　modified　graphene　oxide　(ZGO)　with　polyether　block　amide　(PEBA)　was　deposited　on　ceramic　tubular　substrate　to　prepare　composite　membrane　for　bio-butanol　recovery.　ZGO　laminates　can　be　used　to　form　transport　channels　for　butanol　molecules　to　enhance　the　permeance.　The　affinity　of　laminate　to　butanol　was　improved　because　of　the　hydrophobic　ZIF-8　particles.　Therefore,　the　separation　performance　of　ZGO/PEBA　membrane　was　enhanced.　The　microstructure　and　chemical　property　of　the　ZGO/PEBA　membranes　were　characterized.　Different　preparation　and　operation　conditions　were　also　investigated　to　optimize　the　separation　performance.　Moreover,　ZGO/PEBA　composite　membranes　were　evaluated　in　model　acetone-butanol-ethanol　(ABE)　solution,　which　also　exhibited　high　butanol　recovery　performance.　Therefore,　this　facile　strategy　may　provide　a　potential　application　in　the　commercialized　ABE　fermentation　process.