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Author:

Wang, Xinpeng (Wang, Xinpeng.) | Ye, Qing (Ye, Qing.) (Scholars:叶青) | Liu, Wenyi (Liu, Wenyi.) | Meng, Fanwei (Meng, Fanwei.) | Yang, Fan (Yang, Fan.) | Zhang, Xin (Zhang, Xin.) | Dai, Hongxing (Dai, Hongxing.)

Indexed by:

EI Scopus SCIE

Abstract:

The yCe-xMn/Fe-PILC (x and y are the nominal weight percentages of Mn and Ce, respectively; x = 4.0 wt%, y = 2.0, 4.0, and 6.0 wt%) catalysts were prepared using the impregnation method. Physicochemical properties of the as-prepared materials were measured by means of the XRD, SEM, BET, TPR, XPS, TGA-DSC, and in situ DRIFTS techniques, and their catalytic activities for the selective catalytic reduction of NO with NH3 (NH3-SCR) at low temperatures were evaluated. The 4Ce-4Mn/Fe-PILC showed the highest NO conversion of 95% at 350 degrees C and better resistance to SO2 poisoning than the Ce-free 4Mn/Fe-PILC. The loading of ceria not only increased the concentrations of active Mn4+ species and chemisorbed oxygen (O-ads) species, but also improved redox ability of the 4Ce-4Mn/Fe-PILC. After SO2 poisoning, the concentrations of active Mn4+ and O-ads species in the ceria-loaded samples were decreased by less extents than those in the ceria-free sample. The in situ DRIFTS results further demonstrated that the doping of ceria increased the amount of acid sites, enhanced the formation of NH3 intermediates (i.e., monodentate nitrite and bridging nitrate), and protected the main active Mn4+ species. Therefore, the samples containing ceria possessed better resistance to SO2 poisoning.

Keyword:

Iron-pillared clay NH3-SCR Manganese oxide loading SO2 resistance Ceria doping

Author Community:

  • [ 1 ] [Wang, Xinpeng]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Ye, Qing]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Wenyi]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Meng, Fanwei]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Yang, Fan]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Xin]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Fac Environm & Life, Dept Chem Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Ye, Qing]Beijing Univ Technol, Fac Environm & Life, Dept Environm Sci, Beijing 100124, Peoples R China;;

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Source :

REACTION KINETICS MECHANISMS AND CATALYSIS

ISSN: 1878-5190

Year: 2023

Issue: 3

Volume: 136

Page: 1263-1281

1 . 8 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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