收录:
摘要:
As a typical wear-resistant material, TiC particle-reinforced AlCoCrFeNi composite coatings have great advan-tages. In this work, the Mo was added to AlCoCrFeNi-TiC coatings to further improve the wear resistance, which were fabricated as AlCoCrFeNiMox-TiC (x: molar ratio; x = 0, 0.2, 0.5, 0.8) composite coatings by laser cladding. The microstructure evolution, hardness, and wear resistance were investigated in detail. The results show that a ring of (Ti, Mo)C phase is formed in the outer layer of TiC particles due to the substitution of Mo atoms. Based on the first-principles calculations, the lattice constant of (Ti, Mo)C phase is 4.328 angstrom, slightly smaller than that of TiC. More importantly, Mo can significantly reduce the interface energy from 0.27 J center dot m(-2) to -0.18 J center dot m(-2), thus improving the interface stability. The coating matrix (CM) exhibits a spinodal structure of B2 + sigma phase, caused by the generation of sigma phase. The sigma phase has a calculated hardness of about 15.3 GPa, which is undoubtedly conducive to wear resistance of the CM. With the addition of Mo, the hardness of composite coating increases from 611.9 HV0.3 to 822.6 HV0.3. All the coatings present high wear resistance, as evidenced by the abrasive wear mechanisms.
关键词:
通讯作者信息:
电子邮件地址:
来源 :
APPLIED SURFACE SCIENCE
ISSN: 0169-4332
年份: 2023
卷: 623
6 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:26
归属院系: