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作者:

Lv, Xiaoyu (Lv, Xiaoyu.) | Zheng, Zilong (Zheng, Zilong.) | Zhao, Ming (Zhao, Ming.) | Wang, Hanpeng (Wang, Hanpeng.) | Zhuang, Daming (Zhuang, Daming.)

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摘要:

Tandem solar cells usually use a wide band gap absorber for top cell. The band gap of CuIn(1-x)GaxSe2 can be changed from 1.04 eV to 1.68 eV with the ratio of Ga/(In+Ga) from 0 to 1. When the ratio of Ga/(In+Ga) is over 0.7, the band gap of CIGS absorber is over 1.48 eV. CIGS absorber with a high Ga content is a possible candidate one for the top cell. In this work, CuInGa precursors were prepared by magnetron sputtering with CuIn and CuGa targets, and CIGS absorbers were prepared by selenization annealing. The Ga/(In+Ga) is changed by changing the thickness of CuIn and CuGa layers. Additionally, CIGS solar cells were prepared using CdS buffer layer. The effects of Ga content on CIGS thin film and CIGS solar cell were studied. The band gap was measured by PL and EQE. The results show that using structure of CuIn/CuGa precursors can make the band gap of CIGS present a gradient band gap, which can obtain a high open circuit voltage and high short circuit current of the device. With the decrease in Ga content, the efficiency of the solar cell increases gradually. Additionally, the highest efficiency of the CIGS solar cells is 11.58% when the ratio of Ga/(In+Ga) is 0.72. The value of Voc is 702 mV. CIGS with high Ga content shows a great potential for the top cell of the tandem solar cell.

关键词:

CIGS CuIn/CuGa precursors tandem solar cell band gap energy Ga content

作者机构:

  • [ 1 ] [Lv, Xiaoyu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhao, Ming]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 4 ] [Wang, Hanpeng]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 5 ] [Zhuang, Daming]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China

通讯作者信息:

  • [Zhuang, Daming]Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China;;

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来源 :

MATERIALS

年份: 2023

期: 7

卷: 16

3 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:26

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