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Author:

Zhang, Nizi (Zhang, Nizi.) | Tang, Chenliu (Tang, Chenliu.) | Bi, Weixia (Bi, Weixia.) | Sun, Zhirong (Sun, Zhirong.) | Hu, Xiang (Hu, Xiang.)

Indexed by:

EI Scopus SCIE

Abstract:

Efficient removal of antibiotics from the aquatic environment is urgently needed due to their obstinate accumulation and non-biodegradability. In this study, a mesoporous carbon material (ZC-0.5) was successfully synthesized for the adsorption of sulfamethoxazole (SMX), one of the major antibiotics for the treatment of human and animal infections. ZIF-8 as the precursor of ZC-0.5, specifically, using cetyl trimethyl ammonium bromide (CTAB) and sodium laurate (SL) as dual templates and carbonizing at 800 celcius. This novel adsorbent exhibited a high proportion of mesopore (75.64%) and a large specific surface area (1459.73 m(2)center dot g(-1)). The adsorption experiment examined the reusability of ZC-0.5 and that it could retain superior maximum adsorption capacities (167.45 mg center dot L-1) after five cycles of adsorption and desorption. The adsorption process satisfied the pseudo-second-order kinetic (PSO) and mixed first- and second-order kinetic (MOE). It also satisfied the Freundlich and Sips isotherm models. Moreover, thermodynamic calculation indicated the adsorption process was spontaneous, endothermal, and entropy-increasing. Furthermore, plausible adsorption mechanisms were explained through van der Waals force, electrostatic interaction, hydrophobic force, pi-pi interaction, and hydrogen bond. This work offers a new efficient adsorbent for antibiotic elimination.

Keyword:

Adsorption CTAB SL Template SMX ZIF-8 Mesopore

Author Community:

  • [ 1 ] [Zhang, Nizi]Beijing Univ Chem Technol, Coll Chem Engn, Res Grp Water Pollut Control & Water Reclamat, Beijing 100029, Peoples R China
  • [ 2 ] [Tang, Chenliu]Beijing Univ Chem Technol, Coll Chem Engn, Res Grp Water Pollut Control & Water Reclamat, Beijing 100029, Peoples R China
  • [ 3 ] [Bi, Weixia]Beijing Univ Chem Technol, Coll Chem Engn, Res Grp Water Pollut Control & Water Reclamat, Beijing 100029, Peoples R China
  • [ 4 ] [Hu, Xiang]Beijing Univ Chem Technol, Coll Chem Engn, Res Grp Water Pollut Control & Water Reclamat, Beijing 100029, Peoples R China
  • [ 5 ] [Sun, Zhirong]Beijing Univ Technol, Fac Environm & Life, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Hu, Xiang]Beijing Univ Chem Technol, Coll Chem Engn, Res Grp Water Pollut Control & Water Reclamat, Beijing 100029, Peoples R China;;

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Source :

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

ISSN: 0944-1344

Year: 2023

Issue: 21

Volume: 30

Page: 60704-60716

5 . 8 0 0

JCR@2022

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:17

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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