Herein,　two　coating　amorphous　Al2O3　and　Li3PO4　with　different　properties　were　firstly　demonstrated　for　Li/　Nickel　Foam　(Li/NF)　composite　anode　via　atomic　layer　deposition　(ALD)　method　to　form　a　free-standing　Li　host　material　for　dendrite-free　Li　anode.　Impedance　test　shows　that　Li　nucleates　easily　on　Li3PO4　surface　compared　with　NF　and　Al2O3　surface.　Significantly,　scanning　electron　microscope　(SEM)　observation　of　tracing　the　same　site　shows　that　a　large　number　of　lithium　dendrites　were　deposited　on　NF　and　Al2O3　surface,　while　no　dendrite　growth　was　observed　on　Li3PO4　surface.　The　test　of　cells　shows　that　Li@Li3PO4@NF　anode　presents　better　cycling　stability　and　rate　capability.　Li3PO4　reduces　the　nucleation　overpotential　and　the　surface　energy　barrier,　which　can　increase　the　overall　surface　lithiophilic,　so　that　the　entire　surface　is　deposited　uniformly.　This　work　promotes　the　uniform　deposition　of　lithium　and　sheds　light　on　the　development　of　ultrastable　lithium　metal　anode.