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作者:

Ao, Ci (Ao, Ci.) | Yan, Suying (Yan, Suying.) | Zhao, Long (Zhao, Long.) | Zhao, Xiaoyan (Zhao, Xiaoyan.) | Wu, Yuting (Wu, Yuting.)

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EI Scopus

摘要:

In order to solve the problems of low thermal conductivity and easy liquid leakage of a stearic acid (SA), the composite phase change material(PCM) was prepared by adding boron nitride (BN) and expanded graphite (EG) to melted SA, and its thermal conductivity, crystal structure, chemical stability, thermal stability, cycle stability, leakage characteristics, heat storage/release characteristics, and temperature response characteristics were characterized. The results showed that the addition of BN and EG significantly improved the thermal conductivity of the material, and they efficiently adsorbed melted SA. The maximum load of SA was 76 wt. % and there was almost no liquid leakage. Moreover, the melting enthalpy and temperature were 154.20 J • g − 1 and 67.85°C, respectively. Compared with pure SA, the SA/BN/EG composite showed a lower melting temperature and a higher freezing temperature. In addition, when the mass fraction of BN and EG was 12 wt. %, the thermal conductivity of the composite was 6.349 W • m−1 • K−1, which was 18.619 times that of SA. More importantly, the composite showed good stability for 50 cycles of heating and cooling, and the SA / BN / EG-12 hardly decomposes below 200°C, which implies that the working performance of the composite PCM is relatively stable within the temperature range of 100°C. Therefore, the composite can exhibit excellent thermal stability in the field of building heating. © 2022

关键词:

Thermal conductivity Phase change materials Crystal structure Thermodynamic stability Melting Chemical stability Stearic acid Boron nitride III-V semiconductors Heat storage Graphite Nitrides

作者机构:

  • [ 1 ] [Ao, Ci]College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot; 010051, China
  • [ 2 ] [Yan, Suying]College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot; 010051, China
  • [ 3 ] [Zhao, Long]College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot; 010051, China
  • [ 4 ] [Zhao, Xiaoyan]College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot; 010051, China
  • [ 5 ] [Wu, Yuting]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing; 100124, China

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来源 :

Energy and Built Environment

年份: 2023

期: 5

卷: 4

页码: 557-567

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SCOPUS被引频次: 17

ESI高被引论文在榜: 0 展开所有

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