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作者:

Gao, Qi (Gao, Qi.) | Han, Shuai (Han, Shuai.) | Ye, Qing (Ye, Qing.) (学者:叶青) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Kang, Tianfang (Kang, Tianfang.) (学者:康天放) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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Scopus SCIE

摘要:

Lanthanide (La, Ce, Nd, Gd, Tb, Ho or Lu)-doped Cu-SAPO-18 samples were prepared using the ion-exchange method. Physicochemical properties of the samples were systematically characterized by a number of analytical techniques, and the effects of lanthanide doping on catalytic activity and hydrothermal stability of the Cu-SAPO-18 catalysts for the NH3-SCR reaction were examined. It is shown that the doping of lanthanide elements could affect the interaction between the active components (copper ions) and the AEI-structured SAPO-18 support. The inclusion of some lanthanides significantly slowed down hydrolysis of the catalyst during hydrothermal aging treatment process, leading to an enhanced catalytic activity at both low and high temperatures and hydrothermal stability. In particular, Ce doping promoted the Cu2+ ions to migrate to the energetically favorable sites for enhancement in catalytic activity, whereas the other lanthanide ions exerted little or an opposite effect on the migration of Cu2+ ions. Additionally, Ce doping could improve hydrothermal stability of the Cu-SAPO-18 catalyst by weakening hydrolysis of the catalyst during the hydrothermal aging treatment process. Ce doping increased the catalytic activity of Cu-SAPO-18 at low and high temperatures, which was attributed to modifications of the redox and/or isolated Cu2+ active centers.

关键词:

NH3-SCR selective catalytic reduction lanthanide doping SAPO-18-incorporated Cu catalyst hydrothermal stability

作者机构:

  • [ 1 ] [Gao, Qi]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Han, Shuai]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Ye, Qing]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Kang, Tianfang]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Coll Environm & Energy Engn,Dept Chem & Chem Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Coll Environm & Energy Engn,Dept Chem & Chem Engn, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

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来源 :

CATALYSTS

年份: 2020

期: 3

卷: 10

3 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:139

被引次数:

WoS核心集被引频次: 14

SCOPUS被引频次: 16

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 3

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