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作者:

Cao, Zhilong (Cao, Zhilong.) | Yi, Juan (Yi, Juan.) | Ding, Yongjie (Ding, Yongjie.) | Sun, Guoqiang (Sun, Guoqiang.) | Yu, Jianying (Yu, Jianying.)

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摘要:

Achieving high-performance recycling of aged SBS modified asphalt will help promote the sustainable devel-opment of transportation infrastructure. The destruction of the SBS cross-linking network is an important reason for the deterioration of the performance of aged SBS modified asphalt. Scientific reconstruction of aged SBS cross-linked network is the key to achieving the performance recovery of aged modified asphalt. In this research, the evolution of chemical structure, molecular weight, thermodynamic properties, multiple stress creep recovery capability and rheological property of SBS during the process of aging degradation and reactive reconstruction were systematically investigated. The results showed that the molecular weight and creep recovery capability of SBS decreased sharply, and its complex modulus and phase angle exhibited a strong temperature and frequency dependence after aging. While the number average molecular weight of aged SBS increased by over 70% after reactive reconstruction, and its thermal-oxygen stability shown better performance as compared with that of fresh SBS. Meanwhile, the glass transition temperature of aged SBS was restored to-43.8 degrees C and-54.9 degrees C after reactive reconstructed by toluene diisocyanate (TDI) and isocyanate pre-polymer. Therefore, isocyanate pre -polymer with flexible long chain structure was more benefit for improving the low-temperature performance of reactive reconstructed aged SBS. Furthermore, the creep recovery ability and complex modulus of aged SBS were all significantly improved, and exhibited dramatically high-elastic properties after reactive reconstruction. And as compared with isocyanate pre-polymer, TDI with benzene ring rigid structure was more conducive to restoring the medium-high temperature rheological properties of aged SBS. Therefore, effective restoration of molecular weight and performance of aged SBS can be achieved by using reaction reconstruction method. This study would provide inspiration and ideas for the high-value recycling of waste polymer modified asphalt.

关键词:

Reactive reconstruction Rheological property Styrene-butadiene-styrene block copolymer Aging degradation Chemical structure

作者机构:

  • [ 1 ] [Cao, Zhilong]Beijing Univ Technol, Dept Rd & Railway Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Ding, Yongjie]Beijing Univ Technol, Dept Rd & Railway Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Sun, Guoqiang]Beijing Univ Technol, Dept Rd & Railway Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Yi, Juan]Wuhan Univ Technol, Coll Mat Sci & Engn, Wuhan 430070, Peoples R China
  • [ 5 ] [Yu, Jianying]Wuhan Univ Technol, Coll Mat Sci & Engn, Wuhan 430070, Peoples R China

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来源 :

CONSTRUCTION AND BUILDING MATERIALS

ISSN: 0950-0618

年份: 2023

卷: 391

7 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:26

被引次数:

WoS核心集被引频次:

SCOPUS被引频次: 15

ESI高被引论文在榜: 0 展开所有

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