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Compared with traditional nanoparticle materials, inorganic nanocomposites with ordered and porous structure are superior in specific surface area and adsorption capacity, showing tremendous application potential in the field of adsorption, separation, catalysis and so forth. Among them, the diatomite are one of the most spectacular examples of natural inorganic ordered porous materials with a unique pattern of nano-sized features. In the past, diatomite were developed and utilized in an extensive pattern, and the major application for diatomite is restricted to building materials, filter fillers, etc. In recent years, the research and utilization of diatomite has gradually become a hot spot in the field of micro and nano-technology, thanks to their unique shapes and ordered porous structures at the micro-and nanoscale, high specific surface area, favorable thermal stability and cost-effectiveness advantages. A series of theoretical and technical problems concerning diatomite are raised in micro-and nano-scale, and the related research results have already applied to industry and people's livelihood. It is not surprising that these promising natural materials with unique structures has been considered as candidate raw materials for energy conversion and storage devices. Nevertheless, diatomite have many limitations such as high resistivity, which are not favourable for energy conversion and storage and other applications. Accordingly, considerable efforts have been paid for optimization of diatomite. Specifically speaking, one approach is to load a particular material with satisfactory electrochemical properties on the surface of diatomite, and the silica hydroxyl group on the surface of diatomite can be used to match the valence bond with the modification material. Meanwhile, porous structure of diatomite with high specific surface area will contribute to greatly improve the electrochemical properties of diatomite based composites. Another approach is to transform diatomite into another kind of material with high conductivity. The application of diatomite-based composite materials in energy storage has attracted extensive attention and exhibited great potential. Three-dimensional porous materials have a wide range of applications in the environmental field. Surface modification can endow diatomite with excellent performance of the three-dimensional porous material. For instance, the arrangement of valence bonds on the surface of nano-metal oxides can be significantly varied by the combination of silicon hydroxyl groups on the surface of diatomite and the nano-metal oxides through hydrogen bonding, thereby affecting the properties of the materials. Besides, a great deal of work has been carried out on the research of diatomite-based composite materials in the environmental field at home and abroad. The functional composites are achieved by controllable deposition of functional materials on diatomite surface. This composite material maintaining the pore structure of diatomite and high specific surface area provides a large number of active sites for functional materials, and significantly improves the performance of diatomite-based composite materials. Diatomite-based composite materials are emerging research subjects, which have been studied and applied in many fields, including supercapacitors, lithium batteries, heavy metal pollutant adsorption, degradation and catalysis. According to the research status of diatomite-based composites both at home and abroad in recent years, the latest progress of application of novel diatomite-based composites in energy storage and pollutant adsorption, degradation and catalysis is demonstrated. © 2019, Materials Review Magazine. All right reserved.
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Materials Reports
ISSN: 1005-023X
年份: 2019
期: 5
卷: 33
页码: 1483-1489