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作者:

Fang, De Cai (Fang, De Cai.) | Zheng, Jia Yu (Zheng, Jia Yu.) | Han, Chang Bao (Han, Chang Bao.) | Zhao, Wen Kang (Zhao, Wen Kang.) | Lu, Yuan Gang (Lu, Yuan Gang.) | Sun, Bei Chen (Sun, Bei Chen.) | Sun, Ling (Sun, Ling.) | Wang, Xinxin (Wang, Xinxin.) | Yan, Hui (Yan, Hui.)

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EI Scopus SCIE

摘要:

Transition metal oxide MnOx shows great potential in catalytic formaldehyde (HCHO) pollution degradation at room temperature, but it is difficult to effectively overcome the catalyst deactivation caused by the accumulation of intermediates. Hereon, a 3D conductive aerogel catalyst with cellulose nanofibers (CNF) skeleton supported MnOx nanoflowers and carbon black (CB) was prepared by freeze-drying. Based on the aerogel catalyst (MnOx/CB/CNF), an electro-injection-enhanced catalytic oxidation (EICO) strategy was proposed for HCHO degradation by promoting the formation lattice oxygen and reactive oxygen species O*. In the dynamic test (similar to 15 ppm at the weight hourly space velocity (WHSV) of 600000 mL/g(MnOx)center dot h), the HCHO-to-CO2 conversion efficiency of MnOx/CB/CNF by electro-injection can be enhanced to 76.27%, which is 26.4% higher than that without electroinjection, and the corresponding dynamic efficiency did not show a decreasing trend within 72 h. This proposed EICO strategy may realize the efficient and long-term pollutant degradation at room temperature.

关键词:

Catalytic oxidation Conductive aerogel Formaldehyde (HCHO) Manganese dioxide (MnOx) Electron injection

作者机构:

  • [ 1 ] [Fang, De Cai]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zheng, Jia Yu]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Han, Chang Bao]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhao, Wen Kang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Lu, Yuan Gang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Sun, Bei Chen]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Sun, Ling]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Wang, Xinxin]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 9 ] [Yan, Hui]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

年份: 2023

卷: 334

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:20

被引次数:

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SCOPUS被引频次: 23

ESI高被引论文在榜: 0 展开所有

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