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Author:

Xu, Yurui (Xu, Yurui.) | Liu, Xiao (Liu, Xiao.) (Scholars:刘晓) | Jiang, Minghui (Jiang, Minghui.) | Lai, Guanghong (Lai, Guanghong.) | Li, Shiyu (Li, Shiyu.) | Wang, Ziming (Wang, Ziming.) | Cui, Suping (Cui, Suping.)

Indexed by:

EI Scopus SCIE

Abstract:

In the synthesis of functional polycarboxylate superplasticizers (PCEs), ester monomer was usually used as small monomer or macromonomer. However, there were few studies on the co-introduction of small ester monomer and ester macromonomer into one PCE molecule and its effects. In this study, it was found an interesting behavior of competitive hydrolysis between these two ester monomers in diester PCE, which performed higher fluidity of cement paste, greater adsorption amount and shorter prolongation of the induction period of cement hydration due to the competitive hydrolysis. Furthermore, the kinetics of hydrolysis and adsorption of the diester PCE were probed, and the rate order was: ester macromonomer < small ester monomer < diester monomers. This study aims to innovatively reveal the special behavior and mechanism of competitive hydrolysis of PCE using diester monomers in cement-based materials and to provide a theoretical basis for enriching molecular design and innovative application of functional PCEs.

Keyword:

Hydrolysis kinetics Cement paste Molecular design Ester Polycarboxylate superplasticizer Competitive hydrolysis

Author Community:

  • [ 1 ] [Xu, Yurui]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Xiao]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Jiang, Minghui]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Lai, Guanghong]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Shiyu]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Ziming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Cui, Suping]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Xu, Yurui]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 9 ] [Liu, Xiao]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 10 ] [Jiang, Minghui]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 11 ] [Lai, Guanghong]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 12 ] [Li, Shiyu]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 13 ] [Wang, Ziming]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 14 ] [Cui, Suping]Beijing Univ Technol, Fac Mat & Mfg, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China

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Source :

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

ISSN: 0927-7757

Year: 2023

Volume: 671

5 . 2 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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