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Author:

Xu, Huan-Huan (Xu, Huan-Huan.) | Wu, Qiong (Wu, Qiong.) | Yue, Ming (Yue, Ming.) (Scholars:岳明) | Li, Cheng-Lin (Li, Cheng-Lin.) | Li, Hong-Jian (Li, Hong-Jian.)

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EI Scopus SCIE CSCD

Abstract:

Cobalt nanowires with different shapes and sizes were synthesized by reduction of carboxylate salts of Co-II in 1, 2-butanediol using a solvothermal chemical process. The well-crystallized Co nanowires with hexagonal close-packed (hcp) phase are observed and the (002) crystalline direction is along the long axis of nanowires. The morphology control is strongly dependent on the reaction parameters. By varying the amount of capping agent in proper ranges, the effect of reaction parameters on controlling the size and shape of Co nanowires is demonstrated. With the amount of capping agent increasing, the aspect ratio of Co nanowires increases remarkably. However, the magnetic measurement of cobalt nanowires shows that the coercivity of the Co nanocrystals does not increase with the increase in aspect ratio monotonously, which suggests that the tip shape and microstructure also play an important role in the magnetization reversal process of the Co nanocrystals, and the aspect ratio plays a much less role as the ratio value exceeds 11. To further understand the effect of size on the magnetic properties in the Co nanowires, micromagnetic simulations were performed, which confirms that the magnetic properties are barely affected by the aspect ratio larger than 10. The highest coercivity of 624 kA center dot m(-1) is obtained for ellipsoid nanowires with a mean length of 200 nm, which also displays a strong magnetic anisotropy. As a result, the highest energy product of the wires reaches 248 kJ center dot m(-3).

Keyword:

Tip shape Morphology control High energy product Co nanowires

Author Community:

  • [ 1 ] [Xu, Huan-Huan]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wu, Qiong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Yue, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Cheng-Lin]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Hong-Jian]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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ISSN: 1001-0521

Year: 2023

Issue: 6

Volume: 42

Page: 1994-1999

8 . 8 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

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SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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