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作者:

He, Dandan (He, Dandan.) | Wang, Zhiheng (Wang, Zhiheng.) | Deng, Di (Deng, Di.) | Deng, Shujun (Deng, Shujun.) | He, Hong (He, Hong.) (学者:何洪) | Liu, Licheng (Liu, Licheng.)

收录:

EI Scopus SCIE

摘要:

In this work, we report the synthesis of crystalline Cu-SSZ-13 catalyst by using different silica sources, including colloidal silica (silica sol), gelatinous silica (silica gel) and tetraethyl orthosilicate (TEOS). These samples were characterized by various techniques (SEM, XRD, BET, ICP-OES, H-2-TPR, NH3-TPD, XAFS). The sample prepared by using silica sol exhibited regular morphology and uniform particle dispersions. The results also showed that different acidities and Cu ions distributions were present on these Cu-SSZ-13 catalysts. The various silica sources affected the physicochemical properties and subsequent catalytic performances in the selective catalytic reduction of NO by NH3 (NO-SCR). Cu-SSZ-13 from TEOS showed obvious advantage for the catalytic activity at low-temperature region (< 200 degrees C). However, Cu-SSZ-13 from silica gel performed superior overall catalytic activity (200-600 degrees C) in the three samples. Furthermore, Cu-SSZ-13 from silica sol displayed superior hydrothermal stability after the same hydrothermal treatment for the three samples, despite of the similar movement of Cu2+ ions under aging process. Thus, the choice of silica sol as precursor source is more profitable for synthesis of Cu-SSZ-13.

关键词:

Silica sources Hydrothermal stability Cu-SSZ-13 NH3-SCR

作者机构:

  • [ 1 ] [He, Dandan]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 2 ] [Wang, Zhiheng]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 3 ] [Deng, Di]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 4 ] [Deng, Shujun]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 5 ] [He, Hong]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 6 ] [Liu, Licheng]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
  • [ 7 ] [He, Dandan]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 8 ] [Wang, Zhiheng]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 9 ] [He, Hong]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 10 ] [Liu, Licheng]Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

通讯作者信息:

  • [Liu, Licheng]Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

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来源 :

MOLECULAR CATALYSIS

ISSN: 2468-8231

年份: 2020

卷: 484

4 . 6 0 0

JCR@2022

被引次数:

WoS核心集被引频次: 22

SCOPUS被引频次: 23

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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