In　this　study,　23　typical　printing　enterprises　were　selected　in　Beijing-Tianjin-Hebei.　Through　gas　chromatography-mass　spectrometry/flame　ionization　detection　(GC-MS/FID),　46　sets　of　analysis　results　were　obtained　to　quantitatively　analyze　the　emissions　characteristics　of　volatile　organic　compounds　(VOCs)　and　the　ozone　generation　potential　of　these　printing　enterprises.　The　results　show　that　the　emission　concentrations　of　total　VOCs　(TVOCs)　in　exhaust　funnels　of　the　printing　enterprises　varied　greatly,　ranging　from　3.3　mg•m-3to　755.0　mg•m-3.　In　the　printing　stations　of　printing　enterprises,　the　emission　concentrations　of　VOCs　were　129.7-958.4　mg•m-3and　19.1-113.7　mg•m-3in　packaging　and　printing　enterprises　and　publications　printing　enterprises,　respectively.　The　concentration　of　VOCs　emitted　by　packaging　and　printing　enterprises　was　significantly　higher　than　that　of　publications　printing　enterprises,　which　is　related　to　the　use　of　solvent-based　inks.　In　terms　of　VOC　composition,　oxygen-containing　VOCs　were　the　primary　type　of　those　emitted　by　the　printing　station　of　packaging　and　printing　enterprises　and　publications　printing　enterprises,　which　accounted　for　a　ratio　of　32.6%-99.4%,　followed　by　alkanes.　In　terms　of　ozone　generation　potential,　the　average　of　ozone　formation　potential　(OFP)　of　the　printing　enterprises　was　505.5　mg•m-3,　in　which　the　packaging　and　printing　enterprises　was　564.1　mg•m-3,　and　the　publication　printing　enterprises　was　52.9　mg•m-3.　The　average　VOC　source　reactivity　(SR)　emitted　from　the　printing　process　was　1.24　g•g-1;　that　is,　1.24　g　of　O3　was　formed　owing　to　the　unit　mass　of　VOC　emission,　of　which　the　packaging　and　printing　enterprises　was　1.70　g•g-1,　and　the　publication　printing　enterprises　was　0.89　g•g-1.　According　to　the　OFP　and　SR,　the　use　of　environmentally　friendly　ink　can　reduce　the　generation　of　O3　and　promote　air　quality　improvement.　©　2019,　Science　Press.　All　right　reserved.