An all manganese-based oxide nanocrystal cathode and anode for high performance lithium-ion full cells - 文章详情页

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摘要：

Manganese　oxide　nanocrystals　are　of　great　interest　for　producing　advanced　high-performance　lithium　ion　batteries　owing　to　the　shortened　lithium　ion　diffusion　length　and　accelerated　interfacial　charge　transfer　rate.　Here　we　have　developed　a　well-controlled　generic　method　to　synthesize　monodisperse　MnO　nanocrystals,　and　present　a　comparative　study　regarding　the　effect　of　crystallite　size　on　electrochemical　stability.　Nanocrystalline　MnO　with　a　size　of　about　10　nm　shows　the　optimal　lithium-storage　performance.　Notably,　Mn-based　nanocrystals　retain　their　stable　cyclability　and　excellent　high-rate　performance　as　both　the　anode　and　cathode.　The　all-nanocrystal　MnO/C//LMO　Li-ion　full　cells　not　only　significantly　improve　the　electrochemical　properties　of　Mn-based　materials　but　also　open　up　avenues　for　the　future　development　of　various　energy　devices.　©　2019　The　Royal　Society　of　Chemistry.

关键词：

Anodes Cathodes Charge transfer Crystallite size Ions Lithium-ion batteries Manganese oxide Nanocrystalline materials Nanocrystals Oxide minerals

作者机构：

[ 1 ] [Chen, Song]International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology, Ministry of Education, College of Optoelectronic Engineering, Shenzhen University, Shenzhen; 518060, China
[ 2 ] [Chen, Song]Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore; 487372, Singapore
[ 3 ] [Shi, Yumeng]International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology, Ministry of Education, College of Optoelectronic Engineering, Shenzhen University, Shenzhen; 518060, China
[ 4 ] [Shi, Yumeng]Eng. Technol. Res. Ctr. for 2D Mat. Information Function Devices and Systems of Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen; 518060, China
[ 5 ] [Wang, Ye]Key Laboratory of Material Physics, Ministry of Education, School of Physics and Engineering, Zhengzhou University, Zhengzhou; 450052, China
[ 6 ] [Shang, Yang]Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore; 487372, Singapore
[ 7 ] [Xia, Wei]College of Mechanical Engineering, Beijing University of Technology, Beijing Key Laboratory of Nonlinear Vibrations and Strength of Mechanical Structures, Beijing; 100124, China
[ 8 ] [Yang, Hui Ying]Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore; 487372, Singapore

通讯作者信息：

[shi, yumeng]eng. technol. res. ctr. for 2d mat. information function devices and systems of guangdong province, college of optoelectronic engineering, shenzhen university, shenzhen; 518060, china;;[shi, yumeng]international collaborative laboratory of 2d materials for optoelectronics science and technology, ministry of education, college of optoelectronic engineering, shenzhen university, shenzhen; 518060, china

电子邮件地址：

yumeng.shi@szu.edu.cn

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