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Author:

Hou, Zhiquan (Hou, Zhiquan.) | Chen, Meiqi (Chen, Meiqi.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Jing, Lin (Jing, Lin.) | Gao, Ruyi (Gao, Ruyi.) | Pei, Wenbo (Pei, Wenbo.) | Li, Zeya (Li, Zeya.) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

EI Scopus SCIE

Abstract:

Ethylene elimination can effectively inhibit the rapid aging of fruits and vegetables in storage and transportation. Improving the low-temperature activity, moisture resistance, and stability of Pt based catalysts is a challenge for catalytic oxidation of ethylene which is an effective elimination method. Herein, we constructed ultrasmall MnOx cluster (< 1 nm) on Pt particles via an alloy in situ transformation strategy, which created a large number of MnOx/Pt interfaces. Among all of the samples, 1.89Pt(2.20)Mn/TiO2 showed the highest catalytic activity in the oxidation of ethylene at a space velocity of 20,000 mL/(g h): T-50% = 34 degrees C and T-90% = 43 degrees C, specific reaction rate at 35 degrees C = 33.0 mu m degrees l/(g(Pt) s), and turnover frequency at 35 degrees C = 6.5 x 10(-3) s(-1). In addition, Pt2.20Mn/TiO2 also exhibited better water resistance and stability than Pt/TiO2. The results of XPS, H2O-TPD, C2H4-TPD, in situ DRIFTS, and (H2O)-O-18 isotopic tracing characterization revealed that the MnOx/Pt interfacial sites accelerated desorption of CO2 and enhanced the activation of surface active oxygen species (O-2 to O-2(2-)). Meanwhile, the numerous interfaces provide more active sites for ethylene adsorption and activation, reducing the inhibitory effect of adsorbed water on ethylene adsorption. It was concluded that the prohibited CO2 adsorption, and increased adsorbed oxygen species were responsible for the excellent catalytic performance and good stability of 1.89Pt(2.20)Mn/TiO2, while the more active sites for ethylene adsorption and activation were responsible for the good water resistance of 1.89Pt(2.20)Mn/TiO2.

Keyword:

Water resistance Supported noble metal catalyst Bimetallic nanoparticle Isotopic trace Ethylene oxidation

Author Community:

  • [ 1 ] [Hou, Zhiquan]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 2 ] [Chen, Meiqi]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Yuxi]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 4 ] [Deng, Jiguang]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 5 ] [Jing, Lin]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 6 ] [Gao, Ruyi]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 7 ] [Pei, Wenbo]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 8 ] [Li, Zeya]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Fac Environm & Life, Key Lab Beijing Reg Air Pollut Control, Dept Chem Engn,Educ Minist China,Beijing Key Lab G, Beijing 100124, Peoples R China

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Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2023

Volume: 339

2 2 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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