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作者:

Pei, Wenbo (Pei, Wenbo.) | Yang, Kuan (Yang, Kuan.) | Deng, Jiguang (Deng, Jiguang.) | Liu, Yuxi (Liu, Yuxi.) | Hou, Zhiquan (Hou, Zhiquan.) | Wang, Jia (Wang, Jia.) | Feng, Yuan (Feng, Yuan.) | Yu, Xiaohui (Yu, Xiaohui.) | Dai, Hongxing (Dai, Hongxing.)

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EI Scopus SCIE

摘要:

Among the single-atom catalysts (SACs), the bimetallic single-atom catalysts play an increasingly promising role in the oxidative removal of volatile organic compounds (VOCs) due to their high efficiency. However, it remains a significant challenge to resist SO2 poisoning in industrial applications. In this work, we report (i) the synthesis of three-dimensionally ordered mesoporous Fe2O3-supported bimetallic AuPt single-atom (denote as Au1Pt1/ meso-Fe2O3) catalyst via a modified polyvinyl alcohol-protected reduction route; (ii) catalytic performance of the catalysts for methanol oxidation; and (iii) catalytic and SO2-resistant mechanism. It was found that compared with Pt-1/meso-Fe2O3 and Ptnp/meso-Fe2O3, Au1Pt1/meso-Fe2O3 exhibited better catalytic activity for methanol combustion, with the temperature at 90% methanol conversion, TOFnoble metal at 120 degrees C, and apparent activation energy being 137 degrees C at a space velocity of 20 000 mL g(-1) h(-1), 6.51 x 10(-2) s(-1), and 36 kJ mol(-1), respectively. The enhanced activity was associated with the improved reducibility, methanol adsorption ability, and strong interaction between noble metal and support. The reaction pathway was deduced to follow a sequence of methanol -> methoxy species -> formaldehyde -> formic acid -> CO2 and H2O. Furthermore, the order of SO2 resistance was Au1Pt1/meso-Fe2O3 > Pt-1/meso-Fe2O3 > Ptnp/meso-Fe2O3. The good SO2 resistance of the Au1Pt1/meso-Fe2O3 catalyst was attributed to the Au Pt bimetallic single atoms uniformly dispersed on the meso-Fe2O3 with the strong ability of sulfate decomposition and the protection of the active sites by meso-Fe2O3 as a sacrificial site. This work presents a novel way for developing high-performance catalysts for VOCs elimination in the presence of SO2.

关键词:

SO2 resistance Mesoporous iron oxide Volatile organic compound oxidation Bimetallic single-atom catalyst Reaction mechanism

作者机构:

  • [ 1 ] [Pei, Wenbo]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 2 ] [Yang, Kuan]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Yuxi]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 5 ] [Hou, Zhiquan]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Jia]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 7 ] [Feng, Yuan]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 8 ] [Yu, Xiaohui]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Fac Environm & Life Sci, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Key Lab Adv, Beijing 100124, Peoples R China

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来源 :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

年份: 2023

卷: 335

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:20

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SCOPUS被引频次: 32

ESI高被引论文在榜: 0 展开所有

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