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作者:

Li, Yuanli (Li, Yuanli.) | Zhuang, Chunqiang (Zhuang, Chunqiang.) (学者:庄春强) | Qiu, Shi (Qiu, Shi.) | Gao, Junfeng (Gao, Junfeng.) | Zhou, Quan (Zhou, Quan.) | Sun, Zaicheng (Sun, Zaicheng.) | Kang, Zhenhui (Kang, Zhenhui.) | Han, Xiaodong (Han, Xiaodong.)

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EI Scopus SCIE

摘要:

Metal halide perovskites with broad optical absorption and long carrier lifetime are considered as ideal photocatalysts. However, their poor stability in water greatly impedes their application in photocatalytic H-2 evolution because they lose their crystalline structure in water. Herein, we proclaim a new class of photocatalysts: all-inorganic Cs-Cu-Cl perovskite quantum dots (QDs). It exhibits a high photocatalytic hydrogen production rate of similar to 3.1 mmol/g/h without any cocatalyst under AM 1.5-G solar irradiation (100 mW/cm(2)). Especially, it remains the high activity for up to 330 h without apparent deterioration of the hydrogen production rate. Density functional theory (DFT) calculations reveal that the Cu site works as the electron and proton absorption sites as the H-2 production active center. To our best knowledge, there is no report of metal halide perovskites as water-stable photocatalysts. This work opens an innovative way for guiding the exploration of metal halide perovskites photocatalysts for stable photocatalytic H-2 evolution.

关键词:

All-in-one Single-component perovskite Quantum dot Water-stable Photocatalysis

作者机构:

  • [ 1 ] [Li, Yuanli]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Zhuang, Chunqiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhou, Quan]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Han, Xiaodong]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Qiu, Shi]Dalian Univ Technol, Sch Phys, Key Lab Mat Modificat Laser Ion & Elect Beams, Dalian 116024, Peoples R China
  • [ 6 ] [Gao, Junfeng]Dalian Univ Technol, Sch Phys, Key Lab Mat Modificat Laser Ion & Elect Beams, Dalian 116024, Peoples R China
  • [ 7 ] [Qiu, Shi]Dalian Univ Technol, DUT BSU Joint Inst, Dalian 116024, Peoples R China
  • [ 8 ] [Gao, Junfeng]Dalian Univ Technol, DUT BSU Joint Inst, Dalian 116024, Peoples R China
  • [ 9 ] [Sun, Zaicheng]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Dept Chem, Beijing 100124, Peoples R China
  • [ 10 ] [Kang, Zhenhui]Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
  • [ 11 ] [Kang, Zhenhui]Macau Univ Sci & Technol, Macao Inst Mat Sci & Engn MIMSE, MUST SUDA Joint Res Ctr Adv Funct Mat, Taipa 999078, Macao, Peoples R China

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来源 :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

年份: 2023

卷: 337

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:20

被引次数:

WoS核心集被引频次:

SCOPUS被引频次: 29

ESI高被引论文在榜: 0 展开所有

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