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The sol-gel method in combination with spark plasma sintering (SPS) has been applied to prepare NaNbO3 fine-grained ceramics. The results reveal that perovskite type NaNbO3 nano-powders with mean size of 40 nm can be synthesized by an aqueous sol-gel route. Subsequently, using the resulted NaNbO3 nano-powders as precursors, dense ceramics with mean grain size of 1~2 μm are obtained by SPS method. The electrical measurement confirms that the defect dipoles play the roles in assisting antiferroelectric to ferroelectric (AFE-FE) phase transition. Moreover, the dielectric constant exhibits good frequency stability and the loss tangent is as low as 0.018 (1 kHz). © 2018, Science Press. All right reserved.
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