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作者:

Liang, Quan-Ming (Liang, Quan-Ming.) | Liang, Wen-Jun (Liang, Wen-Jun.) (学者:梁文俊) | Zhang, Tie-Jun (Zhang, Tie-Jun.) | Fan, Xing (Fan, Xing.) | Song, Li-Yun (Song, Li-Yun.) | Li, Jian (Li, Jian.) (学者:李坚) | He, Hong (He, Hong.) (学者:何洪) | Yue, Tao (Yue, Tao.)

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摘要:

The Cl-V2O5-WO3/TiO2 catalysts were prepared by impregnation methods. With the Cl ions content increased from 0 to 2.5%, the NO conversion of Cl-V2O5-WO3/TiO2 catalysts increased at first and then decreased. Combined with the experimental results, 1.5% Cl-V2O5-WO3/TiO2 catalyst was the optimal catalyst, NO conversion was higher than 95% in the range of 149-362, and NO conversion was higher than 90% in the temperature range of 145-385. The catalysts were characterized by XRF, BET, XRD, TG, FT-IR and H2-TPR. The specific surface area and pore volume of the catalysts decreased in different degrees after adding SO2 and H2O in reactant gas. The poisoned catalysts deposited sulfur species and contained NH4+ and SO42-. Adding appropriate amount of Cl ions inhibited the formation of side byproducts and enhanced the poisoning resistance of V2O5-WO3/TiO2 catalyst. © 2018, Science Press. All right reserved.

关键词:

Ammonia Catalyst poisoning Chlorine Ions Temperature Titanium compounds Tungsten compounds Vanadium pentoxide

作者机构:

  • [ 1 ] [Liang, Quan-Ming]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 2 ] [Liang, Quan-Ming]Beijing Municipal Institute of Labor Protection, Beijing; 100054, China
  • [ 3 ] [Liang, Wen-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 4 ] [Zhang, Tie-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Fan, Xing]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 6 ] [Song, Li-Yun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 7 ] [Li, Jian]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 8 ] [He, Hong]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 9 ] [Yue, Tao]Beijing Municipal Institute of Labor Protection, Beijing; 100054, China

通讯作者信息:

  • 李坚

    [li, jian]key laboratory of beijing on regional air pollution control, beijing university of technology, beijing; 100124, china

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来源 :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

年份: 2018

期: 11

卷: 46

页码: 1370-1376

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