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摘要:
To achieve the stereoselective and regioselective diamination of alkenes, Xu et al. developed an electro-chemical protocol for the diamination of aryl alkenes with sulfamides by using triarylamine as a redox mediator. The chemistry proceeded in an undivided cell under constant current conditions, featuring not only wide scope of substrates and reasonable yields, but also excellent diastereoselectivity(>20:1 dr) and regioselectivity. This work has been published in the Nature Communications and can be reached at .
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来源 :
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN: 1005-9040
年份: 2020
期: 1
卷: 36
页码: 149-150
3 . 1 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:33
JCR分区:4
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