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作者:

Zhang, Tie-Jun (Zhang, Tie-Jun.) | Li, Jian (Li, Jian.) (学者:李坚) | He, Hong (He, Hong.) (学者:何洪) | Liang, Wen-Jun (Liang, Wen-Jun.) (学者:梁文俊) | Liang, Quan-Ming (Liang, Quan-Ming.)

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摘要:

Sb-V2O5-TiO2 catalysts were prepared by wet impregnation method. The effect of antimony loadings and calcination temperatures on the activity of catalysts were investigated on the basis of 3%V2O5-TiO2. The results indicate that the catalyst with 11% Sb loading, calcined at 500, has the best activity of SCR. The NOx conversion could reach 92% at 170 with the inlet NOx concentration of 0.07%, the O2 volume fraction of 5%, and the space velocity of 27 000 h-1. The H2-TPR data reveal that the increase of activity can be attributed to the promotion of the catalyst oxidation ability by the modifying of antimony. Sb is mainly in the pentavalent antimony form on the surface of the catalyst, and the increase in surface acidity of the catalyst is identified by means of XPS and NH3-TPD. The effects of SO2 and H2O on the catalyst is also studied, showing that the Sb-V2O5-TiO2 has an excellent catalytic activity in the presence of H2O and SO2. FT-IR, TG and pore structure test results suggest that the addition of Sb can effectively inhibit the aggregation of ammonium sulfate on the catalyst surface, thereby improving the service life of the catalyst. © 2017, Science Press. All right reserved.

关键词:

Ammonia Antimony Calcination Catalyst activity Nitrogen oxides Oxide minerals Pore structure Sulfur compounds Temperature Thyristors Titanium Titanium dioxide Vanadium Vanadium pentoxide

作者机构:

  • [ 1 ] [Zhang, Tie-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 2 ] [Li, Jian]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 3 ] [He, Hong]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 4 ] [Liang, Wen-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Liang, Quan-Ming]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China

通讯作者信息:

  • 李坚

    [li, jian]key laboratory of beijing on regional air pollution control, beijing university of technology, beijing; 100124, china

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来源 :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

年份: 2017

期: 6

卷: 45

页码: 740-746

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