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摘要:
Low-temperature co-fired ceramic (LTCC) technology can meet the requirements of device miniaturization and integration. In this work, a novel series of CaMoO4 + x wt.% Li2MoO4 (CMO+ xLMO, x = 0.0-2.5) microwave dielectric ceramics were prepared. The sintering temperature of CMO ceramic significantly declines from 1050 degrees C to 600 degrees C by adding a small amount of LMO. A dissolution-precipitation process at the grain boundary has been demonstrated to be the mechanism for low-temperature sintering through transmission electron microscopy analysis. The low-temperature sintered CMO ceramics present excellent microwave dielectric properties, e.g. CMO+ 1.0 wt.% LMO ceramics sintered at 600 degrees C, er - 14.4, Qxf - 13,060 GHz, rf - - 41.0 ppm/degrees C; CMO+ 2.5 wt.% LMO ceramics sintered at 700 degrees C, epsilon r - 15.1, Qxf - 16,122 GHz, rf - - 43.8 ppm/degrees C, which show great potentials in both LTCC and ULTCC applications.
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来源 :
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN: 0955-2219
年份: 2024
期: 1
卷: 44
页码: 293-301
5 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:3
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