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In order to explore the sonication condition for the ideal cavitation effect and to find out the breakage mechanism of flocs exposed to ultrasound, a model of cavitational bubble and two sorts of simplified models of diffusion-limited aggregation (DLA) floc breakage were established and simulated based on Matlab. The practical flocs breakage patterns were verified through experimental analysis. The results indicated that the cavitation effect decreased as the ultrasonic frequency increased. The increase of ultrasonic density led to the increscent amplitude of cavitation bubble, when the sonication density was 7 W/mL, the radius of cavitation bubbles can be enlarged to 200 times longer and the cavitation effect was fairly good. When the flocs were treated at low energy density (0.03~3 W/mL) and low frequency (25~40 kHz) ultrasonication, surface erosion dominated the breakage effect, which was reflected by decreased radius and increased fractal dimension of flocs. When the energy density exceeds 3 W/mL or the frequency surpasses 40kHz, the large scale fragmentation was the main mechanism, leading to the smaller flocs size and looser structures. The sonication of the frequency of 40 kHz is more beneficial to flocs breakage, with the experimental result that 10minutes' ultrasonication can lead to a dinimutioin rate of 9.8% of the radius and a fractal dimension of 1.394, and the structure of the flocs were more compact. ©, 2015, Chinese Society for Environmental Sciences. All right reserved.
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