• 综合
  • 标题
  • 关键词
  • 摘要
  • 学者
  • 期刊-刊名
  • 期刊-ISSN
  • 会议名称
搜索

作者:

Wang, Le (Wang, Le.) | Bai, Kun (Bai, Kun.) | Lu, Yuquan (Lu, Yuquan.) | Mo, Wenwu (Mo, Wenwu.) | Zhang, Lijuan (Zhang, Lijuan.)

收录:

EI Scopus SCIE

摘要:

Transition metal selenides are regarded as most promising anode materials for sodium ion battery (SIB) due to their high theoretical specific capacity and environment benignly. Yet the severe volume expansion and sluggish kinetics during cycling leading to capacity fading and material pulverizing restrict its application in SIB. Herein, iron selenides (N-FeSe2) with controlled porous structure is synthesized via facile salt template-assisted method. When N-FeSe2 with hierarchical pore structure serves as anode materials for SIB, a highly reversible capacity of 520.4 mA h g-1 is maintained at 1 A g-1 after 100 cycles. Even at 10 A g-1, the capacity still remains 333 mA h g- 1 after 1800 cycles, which shows extraordinary cycle stability. In addition, N-FeSe2 provides excellent diffusion coefficient and high initial Coulomb efficiency (78.9 %), which is attributed to its special hierarchical porous structure and intrinsic pseudocapacitance characteristics. DFT calculations indicate that an increase in vacancy concentration enhances the conductivity of the material, thereby improving its dynamic performance. In this work, a simple and universal synthesis method is developed, and the pore structure and morphology of the final product can be controlled by simple parameter regulation.

关键词:

Sodium ion battery Anode materials Salt template FeSe2

作者机构:

  • [ 1 ] [Wang, Le]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Bai, Kun]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 3 ] [Lu, Yuquan]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [Mo, Wenwu]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Lijuan]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhang, Lijuan]Beijing Univ Technol, Fac Environm & Life, Ctr Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;

电子邮件地址:

查看成果更多字段

相关关键词:

来源 :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

年份: 2023

卷: 592

9 . 2 0 0

JCR@2022

被引次数:

WoS核心集被引频次:

SCOPUS被引频次: 7

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 1

归属院系:

在线人数/总访问数:360/4970821
地址:北京工业大学图书馆(北京市朝阳区平乐园100号 邮编:100124) 联系我们:010-67392185
版权所有:北京工业大学图书馆 站点建设与维护:北京爱琴海乐之技术有限公司