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摘要:
This study introduces a novel PD-hydroxyapatite (HAP) coupled granular sludge process that efficiently produces nitrite while also addressing the issue of phosphorus (P) removal. Three laboratory-scale sequencing batch reactors (SBRs) were operated with varying calcium (Ca) concentrations, the performance of nitrite production, P removal, and the characteristics of PD-HAP granules under increasing nitrate concentrations (200-800 mg N/L) were investigated. Results demonstrated an increase in nitrite production with influent nitrate, with high PD activity maintained even in the presence of elevated nitrite levels. P removal improved as influent nitrate increased to 400 mg N/L but declined thereafter, likely due to the elevated pH promoting carbonate formation, which competed with phosphate for Ca2+. Supplying a higher Ca(2+ )concentration improved P removal, with R3 achieving a maximum removal efficiency of 96.9% at an influent nitrate of 400 mg N/L, surpassing R2 (85.7%) and R1 (70.0%). Additionally, it was observed that PD-HAP granules increased in size with higher nitrate concentrations but turned to be disintegrated with small granules formed when nitrate exceeded 400 mg N/L. However, despite this, the granules still maintained good settleability, with only a slight increase in sludge volume index (SVI5) from 14.8 to 25.9 ml/g MLSS. This study demonstrated the tremendous potential of PD-HAP granular sludge process for treating high-nitrate wastewater in combination with anammox.
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来源 :
CHEMICAL ENGINEERING JOURNAL
ISSN: 1385-8947
年份: 2023
卷: 474
1 5 . 1 0 0
JCR@2022
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