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作者:

Qin, Yuan (Qin, Yuan.) | Li, Yuqing (Li, Yuqing.) | Wang, Zhanjia (Wang, Zhanjia.) | Wu, Haihui (Wu, Haihui.) | Zhang, Lele (Zhang, Lele.) | Liu, Weiqiang (Liu, Weiqiang.) | Yue, Ming (Yue, Ming.) (学者:岳明)

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EI Scopus SCIE

摘要:

With the rapid development of application fields, such as the green energy industry, has resulted in increased demand for magnetic characteristics, especially the coercivity (Hcj). In this paper, two types of (Nd, Dy) -Fe -B magnets with comparable Hcj values were prepared using by grain boundary diffusion (GBD) method and dual alloy (DA) method. The composition, microstructure, domain structure, and magnetization reversal process of GBD and DA magnets were subjected to comparison. Additionally, an analysis of the specific coercivity mechanism was also conducted by fitting the Brown's equation. The results of composition and microstructure analysis revealed the formation of core-shell structural grains were formed in both GBD and DA methods. Specifically, the GBD method exhibited a higher concentration of Dy in the shell, constituting 26.8 % of the total rare earth (RE) content. In contrast the DA magnets had Dy accounting for 15.8 % of the total RE content in the shell. This discrepancy was identified as the primary factor contributing to the superior efficiency in enhancing the coercivity (Hcj) observed in the GBD method. The fitting results showed that GBD magnets were more inclined to nucleate in the core region in grain, whereas DA magnets nucleate at the edge of the grain shell layer. Both the observation of magnetic domains and magnetization reversal processes analysis revealed that the demagnetization process in GBD magnets is more uniform, which leads to better squareness. Our finding can provide theoretical and experimental basis for the preparation of high -performance Nd-Fe-B magnets.

关键词:

Rare earth permanent magnet materials Grain boundary diffusion Coercivity Nd-Fe-B Dual alloy method

作者机构:

  • [ 1 ] [Qin, Yuan]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yuqing]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Zhanjia]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Haihui]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Lele]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 7 ] [Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China

通讯作者信息:

  • 岳明

    [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China;;[Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T

ISSN: 2238-7854

年份: 2024

卷: 29

页码: 1805-1812

6 . 4 0 0

JCR@2022

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SCOPUS被引频次: 9

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